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Magnetite

earth science Maturity 7-9 Next article →

Magnetite is a vital iron-based mineral that plays a major role in both geology and biology. It is a dark, metallic mineral that is often black or brownish-black in color.

Magnetite sample with neodymium magnet
Magnetite sample with neodymium magnet

Chemically, magnetite is known as iron(II,III) oxide or ferrous-ferric oxide. It is one of the most important iron ores on our planet. Most importantly, magnetite is ferrimagnetic. This means it is attracted to magnets and can be magnetized to become a permanent magnet itself. Aside from very rare deposits of native iron, it is the most magnetic mineral found naturally on Earth.

Kristallstruktur Magnetit
Kristallstruktur Magnetit

The magnetic power of magnetite comes from its complex crystal structure. It possesses an inverse spinel structure. In this arrangement, oxygen ions form a face-centered cubic lattice. The iron atoms, or cations, sit in the spaces between these oxygen ions. Specifically, the mineral contains two types of iron: divalent (ferrous) and trivalent (ferric) iron. Half of the trivalent iron cations occupy tetrahedral sites. The other half, along with all the divalent iron cations, occupy octahedral sites. This specific internal organization is what allows the mineral to interact with magnetic fields.

Scientists have used magnetite to unlock many secrets of the Earth's history. In 1915, researchers established the main details of its crystal structure. It was actually one of the first structures ever identified using X-ray diffraction. This technique allows scientists to see exactly how atoms are positioned. Magnetite also acts as a chemical buffer in rocks. For example, the hematite-magnetite buffer, or HM buffer, helps scientists understand the oxygen levels in the environments where rocks formed. By studying the relationship between magnetite and other minerals like hematite or ilmenite, researchers can calculate the oxygen fugacity, or oxygen levels, in ancient magmas.

Magnetite appears in many different geological settings. It is common in igneous and metamorphic rocks as small grains. It also appears in sedimentary rocks, such as banded iron formations. These formations are important because they help scientists infer how the oxygen content of Earth's atmosphere has changed over time. You can even find magnetite in marine sediments as magnetofossils. Some magnetite crystals grow as octahedrons or rhombic-dodecahedra. In certain conditions, such as hydrothermal synthesis, these crystals can grow as large as 1 mm.

HeavyMineralsBeachSand
HeavyMineralsBeachSand

Large deposits of this mineral are found all over the globe. Some areas have massive amounts of magnetite in beach sands, such as in California or New Zealand. In Peru, there are enormous sand dunes covering 250 square kilometers that contain 10% magnetite. In Mauritania, the highest mountain, Kediet ej Jill, is made entirely of magnetite. Other major deposits exist in Sweden, Chile, and Spain. Because magnetite is so magnetic, large quantities can actually interfere with compass navigation. For instance, in Tasmania, highly magnetized rocks can make using a compass very difficult.

In the world of biology, a phenomenon called biomagnetism occurs when living things use magnetite. Some bacteria, called magnetotactic bacteria, produce tiny chains of magnetite called magnetosomes.

Magnetite magnetosomes in Gammaproteobacteria
Magnetite magnetosomes in Gammaproteobacteria

These bacteria use the magnetic particles to navigate. Other animals, like certain birds, have magnetite crystals in their upper beaks. This allows them to sense the Earth's magnetic field for navigation. Even mollusks like chitons use magnetite to coat their teeth, making them hard enough to break down food.

Humans also contain magnetite within various parts of the brain. It can be found in the frontal, parietal, occipital, and temporal lobes, as well as the cerebellum and the hippocampus. The hippocampus is a region specifically linked to learning and memory. While researchers study if this helps humans with magnetoreception, or a magnetic sense, there are also risks. Airborne magnetite from pollution can enter the brain through the olfactory nerve. In some brain samples, these rounded pollution nanoparticles outnumber natural, crystalline magnetite by a ratio of 100 to 1. This is a significant area of ongoing scientific study.

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🖼️ Images & Media (4)
File:Magnetite sample with neodymium magnet.jpg
Magnetite sample with neodymium magnet.jpg
File:Kristallstruktur Magnetit.png
Kristallstruktur Magnetit.png
File:HeavyMineralsBeachSand.jpg
HeavyMineralsBeachSand.jpg
File:Magnetite magnetosomes in Gammaproteobacteria.png
Magnetite magnetosomes in Gammaproteobacteria.png
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