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Magnetic susceptibility

physical science Maturity 7-9 Next article →

Magnetic susceptibility is a fundamental concept in electromagnetism. It measures how much a material becomes magnetized when it is placed in an applied magnetic field. This value is expressed as a dimensionless proportionality constant. It is calculated as the ratio of magnetization to the applied magnetic field intensity. Magnetization is defined as the magnetic dipole moment per unit volume. By measuring this ratio, scientists can understand how much a substance will react to magnetic forces. This measurement is vital because it reveals the internal structure of materials. It provides deep insights into atomic bonding and energy levels.

To understand how this works, we must look at the atomic level. The magnetizability of a material comes from its particles. This process is usually dominated by the magnetic moments of electrons. Electrons are present in every material. In most cases, these electrons are either paired up or pointing in random directions. Because of this randomness, the overall magnetism of the material is zero without an external field. When an external magnetic field is applied, these electron moments can respond. This response can strengthen or weaken the overall field. The underlying reasons for this alignment are complex and involve quantum mechanics.

Most materials fall into two main categories based on their response. The first is paramagnetism. In paramagnetic materials, the magnetic susceptibility is positive. The induced magnetization aligns with the applied field. This causes the magnetic field lines to concentrate within the material. As a result, paramagnetic materials are attracted to regions where the magnetic field is stronger. The second category is diamagnetism. In diamagnetic materials, the susceptibility is negative. The induced magnetization aligns against the applied field. This causes the field lines to be excluded from the material. Consequently, diamagnetic materials are pushed away toward regions of lower magnetic field strength.

Scientists use several different units to describe susceptibility. In the International System of Quantities (SI), volume magnetic susceptibility is a dimensionless quantity. It is related to permeability, which expresses total magnetization and volume. There are also molar magnetic susceptibility and mass magnetic susceptibility. Molar susceptibility is measured in cubic meters per mole (m³/mol). Mass magnetic susceptibility is measured in cubic meters per kilogram (m³/kg). Some researchers still use the older CGS system. In the CGS system, susceptibility values are often multiplied by four to convert them to SI units. For example, the CGS volume susceptibility of water at 20 °C is 0.000024, which is 0.000096 in SI units.

Measuring these values requires specialized equipment. One historical method is the Gouy balance. In this setup, a sample is hung between the poles of an electromagnet. Scientists measure the change in the sample's weight when the magnet is turned on. This change in weight is proportional to the susceptibility. Modern high-end systems often use a superconductive magnet. Another common tool is the Evans balance. This device measures the force change on a strong, compact magnet when a sample is inserted. For liquid samples, scientists use Nuclear Magnetic Resonance (NMR) techniques. They can measure how the NMR frequency depends on the sample's shape or orientation.

Magnetic susceptibility is not always a simple number. For many crystals, it is a tensor rather than a scalar. This means the magnetic response depends on the orientation of the sample. The magnetization might occur in a direction different from the applied field. In ferromagnetic crystals, the relationship between magnetization and the field is also non-linear. To handle this, scientists use differential susceptibility. This is a more general definition used when the relationship changes based on the field strength. In metals under strong fields, a phenomenon called the De Haas–Van Alphen effect occurs. This causes the differential susceptibility to oscillate as a function of the magnetic field.

This science has massive practical applications in Earth sciences. Geologists use magnetic susceptibility to analyze rocks and understand the Earth's history. A technique called Anisotropy of Magnetic Susceptibility (AMS) helps determine the direction of ancient currents. It can also show the flow direction of injected magma or tectonic strain. In the oil industry, susceptibility helps locate hydrocarbon deposits. In 2014, research in western Ukraine showed that prospective oil locations had higher mass-specific magnetic susceptibility. It can also help distinguish between different types of crude oil. Additionally, it allows experts to quantify clay content in certain reservoirs by measuring minerals like illite and quartz.

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