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Diamagnetism

physical science Maturity 7-9 Next article →

Diamagnetism is a fundamental property of matter where a material is repelled by a magnetic field. When an external magnetic field is applied to a substance, it induces an internal magnetic field that points in the opposite direction. This opposing field creates a repulsive force that pushes the material away from the magnetic source. While many people think of magnetism as an attractive force, such as with iron, diamagnetism is a universal phenomenon. In fact, diamagnetism is a quantum mechanical effect that occurs in all materials.

Diamagnetic material interaction in magnetic field
Diamagnetic material interaction in magnetic field

The mechanism behind this repulsion involves the behavior of electrons. Electrons generally reside in orbitals, which can be thought of as tiny loops of electric current. When a magnetic field is introduced, it changes the orbital motion of these electrons. This change induces magnetic dipole moments within the atoms or molecules. These induced moments align themselves in a direction opposite to the external field. Because the induced field opposes the applied field, the material experiences a push.

EfektMeisnera
EfektMeisnera

Scientists categorize materials based on how they respond to these magnetic forces. In most substances, diamagnetism is a very weak effect. This is because other forms of magnetism, like paramagnetism or ferromagnetism, are much stronger. Paramagnetic and ferromagnetic materials are attracted to magnetic fields because their internal magnetic dipoles align with the external field. In these cases, the strong attractive force overcomes the weak diamagnetic repulsion. A substance is only called a "diamagnet" when the diamagnetic response is the strongest effect present.

Diamagnetic graphite levitation
Diamagnetic graphite levitation

In chemistry, a simple rule helps identify whether a particle is diamagnetic or paramagnetic. If all the electrons in an atom, ion, or molecule are paired, the substance is diamagnetic. If the particle has any unpaired electrons, it is paramagnetic. This distinction is crucial for understanding how different elements will react to magnetic environments. Many common substances are diamagnetic, including water, wood, petroleum, and most plastics. Several metals also show this property, such as copper, gold, silver, mercury, and lead.

Diamagnetic graphite levitation
Diamagnetic graphite levitation

The history of this discovery began in 1778 when Anton Brugmans observed that bismuth was repelled by magnetic fields. In 1845, Michael Faraday conducted experiments to demonstrate that this was a universal property of matter. Faraday concluded that every material responds to a magnetic field in some way. On a suggestion from William Whewell, Faraday used the term "diamagnetic." The prefix "dia-" means to go through or across. Faraday later adjusted the term to the noun "diamagnetism."

While diamagnetism is usually too weak to notice, some materials show extreme versions of this effect. Superconductors are considered perfect diamagnets. This is due to the Meissner effect, where a superconductor entirely expels any magnetic field from its interior.

EfektMeisnera
EfektMeisnera

Other materials show much higher susceptibility than water. For example, the magnetic susceptibility of water is approximately -0.91 x 10⁻⁵. Bismuth is one of the strongest common diamagnets with a susceptibility of -16.6 x 10⁻⁵. Pyrolytic carbon is even more extreme, reaching a susceptibility of -40.9 x 10⁻⁵ in one plane.

Diamagnetic graphite levitation
Diamagnetic graphite levitation

Because diamagnets are attracted to magnetic field minima, they can achieve stable levitation. This allows objects to float without consuming any power. A thin slice of pyrolytic graphite can float above permanent magnets at room temperature. Scientists have used even more powerful magnetic fields to achieve spectacular results. In the Netherlands, researchers successfully levitated water and even a live frog. In 2009, NASA's Jet Propulsion Laboratory levitated mice using a superconducting magnet.

Frog diamagnetic levitation
Frog diamagnetic levitation

These experiments help researchers study how life behaves in microgravity, which is useful for understanding bone and muscle mass in space.

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File:Diamagnetic graphite levitation.jpg
Diamagnetic graphite levitation.jpg
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Diamagnetic material interaction in...
File:EfektMeisnera.svg
EfektMeisnera.svg
File:Frog diamagnetic levitation.jpg
Frog diamagnetic levitation.jpg
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