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Litmus

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Litmus is a water-soluble mixture of various dyes. These dyes are extracted from several different species of lichens.

Lackmus
Lackmus

It serves as one of the oldest forms of a pH indicator. A pH indicator is a substance that changes color to show acidity or alkalinity. Most people use litmus by absorbing the dye into filter paper. This creates litmus paper, a common tool for testing materials. It helps scientists place different substances on a pH scale.

Litmus paper
Litmus paper

The mechanism of litmus relies on specific chemical reactions. Red litmus contains a weak diprotic acid. When this red litmus is exposed to a basic compound, a reaction occurs. The hydrogen ions in the acid react with the added base. This reaction forms a conjugate base from the litmus acid. This new conjugate base has a distinct blue color. Therefore, wet red litmus paper turns blue in an alkaline solution.

7-hydroxyphenoxazone
7-hydroxyphenoxazone

Litmus paper reacts differently depending on the substance it touches. Blue litmus paper turns red when it is in an acidic medium. Conversely, red litmus paper turns blue in a basic or alkaline medium. If the paper remains purple, the substance is considered neutral. These color changes occur across a specific pH range from 4.5 to 8.3. You can also use wet litmus paper to test for water-soluble gases. For example, ammonia gas is alkaline and will turn red paper blue.

Litmus paper
Litmus paper

There are many different species of lichens that provide these dyes. Some sources include Roccella tinctoria from South America. Other species like Roccella fuciformis are found in Angola and Madagascar. Roccella pygmaea grows in Algeria, while Lecanora tartarea is found in Norway and Sweden. Other species include Variolaria dealbata and Ochrolechia parella. Currently, the main sources are Roccella montagnei from Mozambique and Dendrographa leucophoea from California.

Parmelia sulcata
Parmelia sulcata

The history of litmus stretches back many centuries. The name comes from the Old Norse word "litmosi." This term translates to "colour moss" or "colouring moss." The word is recorded in a Norwegian law codex from 1316. This document discussed customs and excise duties on furs and pelts. Around the year 1300, the Catalan physician Arnaldus de Villa Nova used litmus. He used the substance to study the properties of acids and bases.

Parmelia sulcata
Parmelia sulcata

Chemically, the litmus mixture is quite complex. It has the CAS number 1393-92-6. The mixture contains between 10 and 15 different dyes. These components are likely similar to orcein, but in different proportions. The principal constituent of litmus has an average molecular mass of 3300. The ability to act as an indicator comes from a 7-hydroxyphenoxazone chromophore. A chromophore is the part of a molecule responsible for its color.

7-hydroxyphenoxazone
7-hydroxyphenoxazone

It is important to note that other reactions can change the color. Litmus is not always acting as a pH indicator. For instance, chlorine gas can turn blue litmus paper white. This happens because hypochlorite ions are present in the gas. These ions bleach the litmus dye. This specific chemical reaction is irreversible. This means the color change cannot be undone.

Lackmus
Lackmus

Litmus connects to many different fields of science. It is used in chemistry to identify substances. It also relates to biology through the study of lichens. The study of how these dyes work involves complex molecular structures. Scientists use these properties to understand the chemical balance of various solutions. This makes litmus a fundamental tool in both historical and modern science.

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File:Lackmus.jpg
Lackmus.jpg
File:7-hydroxyphenoxazone.svg
7-hydroxyphenoxazone.svg
File:Parmelia sulcata.jpeg
Parmelia sulcata.jpeg
File:Litmus paper.JPG
Litmus paper.JPG
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