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Acid

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An acid is a specific type of molecule or ion. It is defined by its ability to interact with other substances through chemical reactions. In a strict sense, an acid refers to the solute itself. However, people often use the word to describe an aqueous solution. These solutions are characterized by a sour taste and the ability to turn blue litmus paper red. Acids can also react with bases and certain metals, such as calcium, to form salts.

Zn reaction with HCl
Zn reaction with HCl

Chemists use different frameworks to define how acids function. The first is the Arrhenius definition, which focuses on aqueous solutions. An Arrhenius acid is a substance that increases the concentration of hydrogen cations, or H+ ions, when added to water. In these solutions, these protons do not exist alone. Instead, they join with water to form hydronium ions, written as H3O+. Because of this, an Arrhenius acid can also be described as a substance that increases the concentration of hydronium ions in a liquid.

Arrhenius2
Arrhenius2

A second, more general framework is the Brønsted–Lowry theory. In 1923, Johannes Nicolaus Brønsted and Thomas Martin Lowry independently developed this idea. They defined an acid as a proton donor. This means the acid is a species that gives a proton to a base. This theory is more versatile than the Arrhenius model. It can describe reactions that happen in non-aqueous solvents or even in the gas phase. For example, hydrogen chloride and ammonia can react to form solid ammonium chloride without any water present.

Acetic-acid-dissociation-3D-balls
Acetic-acid-dissociation-3D-balls

A third category is known as a Lewis acid. This concept was also proposed in 1923 by Gilbert N. Lewis. A Lewis acid is an electron pair acceptor. Unlike the other definitions, this does not require the movement of a proton. Instead, the acid forms a covalent bond by accepting a pair of electrons from another species. An example is boron trifluoride. Its boron atom has a vacant orbital that allows it to accept an electron pair from a base like ammonia.

LewisAcid
LewisAcid
Hydrochloric acid ammonia
Hydrochloric acid ammonia

Acids vary greatly in their strength and chemical behavior. We measure this strength using the acid dissociation constant, known as Ka. This constant represents the equilibrium between an acid and its conjugate base. A stronger acid has a higher Ka value. This indicates the acid has a greater tendency to lose its proton. Because these values can span many orders of magnitude, scientists often use pKa. The pKa is the negative logarithm of Ka, so a smaller pKa indicates a stronger acid.

Titration alanine
Titration alanine

We also use the pH scale to describe acidity in solutions. A solution is considered acidic if its pH is less than 7. The pH value is the negative logarithm of the hydronium ion concentration. A lower pH number signifies a higher concentration of hydrogen cations. This means the solution is more acidic. In an acidic solution, the concentration of hydronium ions is greater than 10−7 moles per liter.

Tumbler of cola with ice
Tumbler of cola with ice

Many different substances act as acids in our daily lives. Common examples include acetic acid, which is the main component in vinegar. Citric acid is found in many citrus fruits. In the human body, hydrochloric acid is found in gastric acid within the stomach. This acid is essential because it activates digestive enzymes. Other acids, like sulfuric acid, are used in car batteries. While many strong acids are corrosive, there are exceptions like boric acid.

Aminoacid
Aminoacid
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🖼️ Images & Media (9)
File:Zn reaction with HCl.JPG
Zn reaction with HCl.JPG
File:Arrhenius2.jpg
Arrhenius2.jpg
File:Acetic-acid-dissociation-3D-balls.png
Acetic-acid-dissociation-3D-balls.png
File:LewisAcid.png
LewisAcid.png
File:Hydrochloric acid ammonia.jpg
Hydrochloric acid ammonia.jpg
File:Titration alanine.jpg
Titration alanine.jpg
File:Tumbler of cola with ice.jpg
Tumbler of cola with ice.jpg
File:Aminoacid.png
Aminoacid.png
File:Aspirin-skeletal.svg
Aspirin-skeletal.svg
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