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Lewis structure

physical science Maturity 11-13 Next article →

A Lewis structure is a chemical diagram used to visualize molecular bonding. These diagrams are also known as Lewis dot formulas or electron dot structures. They show how atoms connect within a molecule and where lone pairs of electrons exist. A lone pair is a pair of electrons that is not shared in a bond.

Ammonia Lewis structure
Ammonia Lewis structure

These structures are essential for understanding the electronic architecture of many chemical systems. They help scientists predict how molecules will react with one another.

To construct a Lewis structure, one must follow a specific sequence of steps. First, you calculate the total number of valence electrons. Valence electrons are the electrons in the outermost shell that participate in bonding. For a neutral molecule, this total equals the sum of the valence electrons from every atom.

Freie Elektronenpaare Wasser V3
Freie Elektronenpaare Wasser V3

Next, you draw a single line between each pair of connected atoms. Each line represents a single bond, which consists of two shared electrons. After the bonds are drawn, you distribute the remaining electrons as dots. You typically place these dots on the outer atoms first, then move to the central atoms.

Most atoms follow the octet rule during this process. The octet rule states that atoms are most stable when they have eight electrons in their valence shell. Hydrogen is a notable exception to this rule. Hydrogen follows the duplet rule, meaning it only needs two electrons to complete its shell.

Freie Elektronenpaare Wasser V3
Freie Elektronenpaare Wasser V3

If an atom has fewer than eight electrons after the initial distribution, you must adjust the structure. You can do this by taking a lone pair from a neighboring atom and turning it into a bonding pair. This creates a double or triple bond between the atoms.

Gilbert N. Lewis introduced this method in his 1916 article, "The Atom and the Molecule." Even though the scientific understanding of the early twentieth century was limited, his work was highly effective. Lewis structures can be drawn for any covalently bonded molecule or coordination compound. Today, they remain a fundamental tool for both professional chemists and students. They provide a clear way to represent the complex reality of chemical interactions.

When working with ions, the rules for electron counting change slightly. For a polyatomic ion, you must account for the overall charge. A negative ion, or anion, requires adding extra electrons to the total count. A positive ion, or cation, requires having fewer electrons than a neutral molecule.

Nitrite-ion-lewis-canonical
Nitrite-ion-lewis-canonical

To properly denote an ion, you must place the entire structure inside large brackets. The charge is then written as a superscript outside the upper right corner of the brackets.

Sometimes, a single diagram cannot accurately represent a molecule. This occurs during resonance, where multiple valid structures can be drawn for the same ion or molecule. For example, the nitrite ion can be drawn with the double bond on different oxygen atoms.

Nitrite-ion-lewis-canonical
Nitrite-ion-lewis-canonical

Instead of the molecule switching between these forms, it exists as a resonance hybrid. This hybrid is an average of all the possible resonance structures. Chemists represent this by placing double-headed arrows between the different structures. You can also use dashed lines to represent these partial bonds.

To ensure accuracy, chemists use a concept called formal charge. Formal charge is the apparent electronic charge of an atom within a structure. It is calculated by taking the number of valence electrons in a free atom and subtracting the electrons assigned to that atom in the Lewis structure. In this calculation, electrons in covalent bonds are split equally between the atoms.

Nitrite-ion-lewis-canonical
Nitrite-ion-lewis-canonical

The sum of all formal charges in a neutral molecule must equal zero. For an ion, the sum of the formal charges must equal the charge of the ion.

Finally, Lewis structures can be simplified for specific uses. In organic chemistry, scientists often use condensed structural formulas or skeletal formulas. A skeletal formula, also called a bond-line diagram, is a very compact way to show carbon skeletons. In these diagrams, carbon atoms are represented by the vertices of lines rather than the letter C. Hydrogen atoms attached to carbon are not shown but are inferred by the number of bonds.

Butane simple
Butane simple

These shorthand methods allow for much faster communication of complex molecular shapes.

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File:Ammonia Lewis structure.svg
Ammonia Lewis structure.svg
File:Nitrite-ion-lewis-canonical.svg
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Butane simple.svg
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