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Isotopes of uranium

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Uranium is a naturally occurring radioactive element found in the Earth's crust.

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It is unique because it has no stable isotopes. This means every version of uranium is a radioisotope. A radioisotope is an atom that is unstable and will eventually decay. Uranium exists in many different forms called isotopes. These isotopes differ by their mass and how they behave. Some stay around for billions of years. Others break down in mere minutes. The standard atomic weight for natural uranium is 238.02891(3).

Natural uranium is made of three main isotopes. Uranium-238 is the most common, making up about 99.274% of all natural uranium. Uranium-235 is much rarer, accounting for only about 0.72%. Finally, uranium-234 is a tiny part of the mix, appearing at about 0.005%.

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These isotopes decay at constant rates. Scientists use these rates for radiometric dating. This process helps them determine the age of rocks and Earth itself. By comparing the ratio of a parent isotope to its daughter product, they can calculate time.

Uranium-238 is a very stable radioisotope with a massive half-life. A half-life is the time needed for half of a sample to decay. For uranium-238, this is 4.463 billion years. This duration is roughly the age of the Earth. While it is not fissile, it is considered fertile. A fissile material can split and sustain a chain reaction. A fertile material can absorb a neutron to eventually become fissile. When uranium-238 absorbs a neutron, it becomes uranium-239. This isotope decays into neptunium-239, which then decays into plutonium-239. Plutonium-239 is a fissile material used for energy.

Uranium-235 is the only fissile isotope found in significant amounts in nature. It was discovered by Arthur Jeffrey Dempster in 1935. It has a half-life of 704 million years. This isotope is vital for nuclear reactors and weapons. It can undergo fission, which is the splitting of an atom. This happens when it captures a thermal neutron, which is a slow-moving neutron. In a reactor, about five out of six neutron captures result in fission. The remaining one results in neutron capture to form uranium-236. A large enough mass of uranium-235 can sustain a critical chain reaction.

Scientists can also produce other isotopes through specific processes. Uranium-233 is a fissile isotope bred from thorium-232. This happens through neutron bombardment, where a thorium atom absorbs a neutron. The thorium becomes thorium-233, which lasts only 22 minutes. It then beta decays into protactinium-233. This isotope has a half-life of 27 days before it becomes uranium-233. Uranium-233 has a half-life of about 160,000 years. It has been used in experimental reactors and proposed for wider fuel use.

Other isotopes play different roles in nuclear science. Uranium-234 occurs naturally as a decay product of uranium-238. It makes up only 55 parts per million in natural uranium. Its half-life is 245,500 years. Uranium-236 is often seen as a nuisance in spent nuclear fuel. It has a half-life of 23 million years and is neither fissile nor fertile. Uranium-237 was discovered by Yoshio Nishina in 1940. It has a short half-life of about 6.75 days. Finally, uranium-232 is a side product in the thorium cycle. It has a half-life of 68.9 years. It produces intense gamma radiation, which makes handling related materials difficult.

These isotopes connect deeply to how we manage energy and waste. For example, uranium-234 can be converted into uranium-235 in a reactor. This happens because it absorbs slow neutrons. Understanding these complex chains is essential for nuclear engineering. It helps scientists control reactors and manage radioactive byproducts. The study of these tiny particles shapes our understanding of the physical world.

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