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Iron oxide

physical science Maturity 5-7 Next article →

Iron oxide is a chemical compound made of iron and oxygen. These compounds are widespread throughout the natural world. They play vital roles in many geological and biological processes. Iron oxides are also used as iron ores to create metal. They serve as pigments, catalysts, and ingredients in thermite.

Almindeligt rust - jernoxid
Almindeligt rust - jernoxid

Even our own bodies use these materials. For example, iron occurs in hemoglobin. Because they are so versatile, they are important to both nature and human industry.

To understand these compounds, we must look at their chemical structure. Many iron oxides are non-stoichiometric. This means the ratio of iron to oxygen atoms is not always a simple whole number. Iron can exist in different oxidation states. These states are called ferrous, which is Fe(II), and ferric, which is Fe(III).

Red and green iron oxides
Red and green iron oxides

Some compounds contain only one type, while others contain a mixture of both. These atoms arrange themselves into specific geometric shapes. They adopt either octahedral or tetrahedral coordination geometry to form their structures.

There are several distinct types of iron oxides found on Earth. Only a few are significant at the Earth's surface. Wüstite is an oxide of Fe(II), known as FeO. Hematite is an oxide of Fe(III), known as Fe2O3. There is also a mixed oxide called magnetite, which is Fe3O4. Magnetite contains both ferrous and ferric iron.

Red and green iron oxides
Red and green iron oxides

Other forms of Fe2O3 include alpha, beta, gamma, and epsilon phases. There are also oxide-hydroxides, such as goethite and lepidocrocite. These are related to the class of compounds known as ferric oxyhydroxides.

Humans have utilized these minerals for thousands of years. The earliest recorded uses were for decoration. In the 15,000s BC, people in parts of Asia used iron oxide for cave art. At that time, they used the pigment without any adhesive agent to hold it to the surface.

IronOxidePigmentUSGOV
IronOxidePigmentUSGOV

Today, we use them as inexpensive and durable pigments. They provide colors in the earthy range, including yellow, orange, red, brown, and black. They are used in paints, coatings, and colored concrete. Some are even used as a food coloring labeled E172.

In modern industry, iron oxides are essential for making metal. Almost all iron ores are oxides. This makes them necessary precursors to iron metal and various alloys. In blast furnaces and related factories, these oxides are converted into metal. This process requires a reducing agent, such as various forms of carbon.

IronOxidePigmentUSGOV
IronOxidePigmentUSGOV

This chemical change allows us to turn raw ore into the strong metal used in construction and tools.

Specific properties make certain oxides very useful for technology. Magnetite is a component used in magnetic recording tapes. Iron oxides also have specific rates of thermal expansion. For example, the coefficient of thermal expansion for Fe2O3 is 14.9 x 10⁻⁶ °C⁻¹. The value for FeO is 12.1 x 10⁻⁶ °C⁻¹. Magnetite has a value greater than 9.2 x 10⁻⁶ °C⁻¹. These measurements are important for engineers who use these materials in different environments.

Biology also relies on the chemistry of iron. In many organisms, iron is stored in a form called ferritin. This is a ferrous oxide that is encased in a solubilizing protein sheath.

Almindeligt rust - jernoxid
Almindeligt rust - jernoxid

Certain species of bacteria also interact with these compounds. Bacteria such as Shewanella oneidensis, Geobacter sulfurreducens, and Geobacter metallireducens use iron oxides as terminal electron acceptors. This shows how iron oxide is deeply connected to the cycles of life and the movement of electrons in the natural world.

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File:Almindeligt rust - jernoxid.jpg
Almindeligt rust - jernoxid.jpg
File:IronOxidePigmentUSGOV.jpg
IronOxidePigmentUSGOV.jpg
File:Red and green iron oxides.jpg
Red and green iron oxides.jpg
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