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Hydrogen spectral series

physical science Maturity 9-11 Next article →

Hydrogen is the simplest atom in our universe.

Hydrogen transitions
Hydrogen transitions

It has a nucleus and one electron that moves around it. This electron stays in specific energy levels. You can think of these levels like steps on a ladder. Each step has a set amount of energy. When an electron jumps from a high step to a lower step, it releases energy. This energy comes out as a tiny bit of light called a photon.

05-07-2015 Problem 7.64
05-07-2015 Problem 7.64

Because the steps are at fixed heights, the light always has the same energy. This creates specific lines of color called a spectral series.

Scientists group these light lines into series based on where the electron lands.

Hydrogen spectrum
Hydrogen spectrum

If an electron falls to the very first energy level, it creates the Lyman series. These lines are in the ultraviolet band. If the electron falls to the second level, it makes the Balmer series. Some of these lines are part of the visible light we can see. For example, the H-alpha line is a bright red color.

Emission H-α 656.3
Emission H-α 656.3

If it falls to the third level, it creates the Paschen series. These lines are in the infrared band. Other series like Brackett and Pfund also fall in the infrared range.

Many smart people helped us understand these patterns over many years.

LymanSeries
LymanSeries

Theodore Lyman discovered the Lyman series between 1906 and 1914. Johann Balmer found a math rule for his series in 1885. Friedrich Paschen observed his series in 1908. Frederick Sumner Brackett found the Brackett series in 1922. August Herman Pfund discovered the Pfund series in 1924. Later, Curtis J. Humphreys found the Humphreys series in 1953. Even in 1972, Peter Hansen and John Strong found a seventh series at the University of Massachusetts Amherst.

There is a special math rule called the Rydberg formula.

Emission spectrum-H
Emission spectrum-H

This formula helps scientists predict the wavelengths of the light. A wavelength is the distance between parts of a light wave. The formula works for any atom that has only one electron. This includes things like the He+ ion. The formula shows that the energy of the light depends on the levels. It also shows that the mass of the nucleus matters. This is because the nucleus moves slightly when the electron jumps.

These tiny jumps of light tell us big secrets about space.

Emission H-β 486
Emission H-β 486

Astronomers use these lines to find hydrogen in far-off stars. They can use the Balmer lines to see if hydrogen is there. They can also calculate red shifts by looking at these lines. This helps them understand how things move in the universe. It is like reading a secret code written in light. By studying these series, we learn how the physical world works.

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🖼️ Images & Media (10)
File:Hydrogen spectrum.svg
Hydrogen spectrum.svg
File:Hydrogen transitions.svg
Hydrogen transitions.svg
File:05-07-2015 Problem 7.64.jpg
05-07-2015 Problem 7.64.jpg
File:LymanSeries.svg
LymanSeries.svg
File:Emission spectrum-H.svg
Emission spectrum-H.svg
File:Emission_H-α_656.3.png
Emission_H-α_656.3.png
File:Emission_H-β_486.png
Emission_H-β_486.png
File:Emission_H-γ_434.0472.png
Emission_H-γ_434.0472.png
File:Emission_H-δ_410.1734.png
Emission_H-δ_410.1734.png
File:Emission_H-ε_397.0075.png
Emission_H-ε_397.0075.png
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