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Herbicide

life science Maturity 9-11 Next article →

Herbicides are chemical substances used to control undesired plants, commonly called weeds.

Sprayed weeds
Sprayed weeds

These tools are vital for modern agriculture and forestry. They allow farmers to protect crops from competition for resources. By managing weeds, herbicides help increase crop yields significantly. Between 1900 and 2000, the use of herbicides, fertilizers, and improved cultivars increased major crop yields by three to six times per acre.

Direktsaat Probleme001
Direktsaat Probleme001

In the United States in 2012, approximately 91% of all herbicide usage by weight was applied in agriculture.

Herbicides are classified by how they act on plants. Selective herbicides target specific weed species while leaving the desired crop unharmed. For example, 2,4-D, mecoprop, and dicamba control many broadleaf weeds but do not harm turf grasses. Non-selective herbicides, sometimes called defoliants, kill plants indiscriminately. These are often used to clear industrial sites, railways, or waste grounds. Common non-selective examples include paraquat, glufosinate, and glyphosate.

Timing and application methods also define how these chemicals work. Preplant herbicides are applied to the soil before planting. Some are mechanically incorporated into the soil to prevent them from breaking down through light or evaporation. Preemergence herbicides are applied before weed seedlings emerge from the soil. These chemicals kill weeds as they grow through the treated zone by affecting cell division. Postemergence herbicides are applied after the weeds have already emerged. These can be absorbed through the leaves, known as foliar absorption, or through the roots.

Herbicide spraying, Carlson Waterfowl Production Area in LaMoure County, ND
Herbicide spraying, Carlson Waterfowl Production Area in LaMoure County, ND

Environmental factors heavily influence how well a herbicide performs. Climatic conditions like humidity, light, and temperature change how a plant absorbs the chemical. High humidity can help foliage-applied herbicides enter a leaf by keeping the spray droplet wet longer. However, intense light may break down some herbicides or cause the leaf cuticle to thicken. This thickening can make it harder for the chemical to be absorbed. Precipitation can also play a dual role. Rain might wash away a spray from leaves, but it can increase the absorption of soil-applied herbicides by the roots.

Modern herbicides work by interfering with the biochemical machinery of the plant. They often mimic natural plant hormones or enzyme substrates to disrupt metabolism. One group is known as ACCase inhibitors. These target acetyl coenzyme A carboxylase, which is part of the first step in lipid synthesis. By stopping this process, they prevent the production of cell membranes in the meristems of grasses. Another group is the ALS inhibitors. These target acetolactate synthase, an enzyme used to synthesize branched-chain amino acids like valine, leucine, and isoleucine. Without these amino acids, the plant cannot synthesize DNA, which eventually leads to death.

History shows that herbicide use has evolved from simple methods to complex chemistry. Before widespread chemical use, people used cultural controls like changing soil pH or salinity. They also used mechanical methods like tillage or flooding. In the late 19th and early 20th centuries, people used inorganic chemicals like arsenic, kerosene, or sulfuric acid. However, these were often toxic, flammable, or corrosive, and they were not very effective. The real revolution began during the Second World War through research in the United Kingdom and the United States.

Major breakthroughs occurred when W. G. Templeman synthesized 2,4-D at Imperial Chemical Industries. This was the first successful selective herbicide. It was commercially released in 1946 and allowed for better control in cereal crops. It works because it kills dicots, which are broadleaf plants, but not most monocots, which are grasses.

Later, the triazine family, including atrazine, was introduced in the 1950s. Atrazine is notable because it can cause groundwater contamination if it is not broken down quickly in the soil. Finally, glyphosate was recognized for its herbicidal activity in the 1960s and marketed as Roundup in 1971. It is now used extensively alongside glyphosate-resistant crop plants.

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Classification of herbicides according to...
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Herbicide spraying, Carlson Waterfowl...
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