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Group 9 element

physical science Maturity 11-13 Next article →

Group 9 is a specific column of chemical elements in the d-block of the periodic table. This family includes cobalt, rhodium, iridium, and the synthetic element meitnerium. These elements are among the rarest of the transition metals. As of 2025, rhodium and iridium are the only non-radioactive metals with higher prices per weight than gold. Members of this group share patterns in their electron configuration. This refers to how electrons are arranged in their outermost shells. These patterns cause the elements to show similar trends in chemical behavior. However, rhodium is a notable exception that deviates from this group pattern.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color

The history of naming this group has changed over time. The modern designation "Group 9" was adopted by the IUPAC in 1990. Before this change, different systems used different names. In the Chemical Abstracts Service "U.S. system," the group was called VIIIB. It was combined with group 8 and group 10. In the older IUPAC "European system," it was simply called VIII. This was also the name used in Mendeleev's original periodic table. These changes helped create a single, modern standard for scientists to follow.

Cobalt is a hard, silvery-white metal with many uses. For centuries, people have used cobalt compounds to create a rich blue color. This color is found in glass, glazes, ceramics, inks, paints, and varnishes. Specifically, cobalt silicate and cobalt(II) aluminate provide this deep blue shade. Cobalt is also vital for modern technology. It is used in lithium-ion batteries and in making high-strength, wear-resistant alloys. In the petroleum industry, cobalt acts as a catalyst. It helps refine crude oil by removing sulfur. Removing sulfur is important because burning it causes polluting acid rain.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color

Cobalt also plays a critical biological role that other group 9 elements do not. It is a key part of cobalamin, which is also known as vitamin B. This is the primary way cobalt exists as an ultratrace element in living things. In the stomachs of ruminant animals, bacteria convert cobalt salts into vitamin B. These animals cannot produce the vitamin themselves. Therefore, a minimal amount of cobalt in soil is necessary for the health of grazing animals. In humans, vitamin B12 helps with important chemical tasks. For example, methylmalonyl coenzyme A mutase helps extract energy from fats and proteins.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color

The discovery of cobalt was a major event in science. A Swedish chemist named Georg Brandt discovered it around 1735. He proved it was a new element and not bismuth. Brandt called it a "semi-metal." This was the first metal discovered since the pre-historical period. All other known metals, like gold or iron, had no recorded discoverers. Cobalt has been found in many ancient places. It appeared in Egyptian sculpture and Persian jewelry from the third millennium BC. It was even found in the ruins of Pompeii, which was destroyed in 79 AD.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color

Rhodium and iridium were discovered in 1803 through very careful chemical processes. William Hyde Wollaston discovered rhodium using platinum ore from South America. He dissolved the ore in aqua regia, which is a mixture of nitric and hydrochloric acids. He then used sodium chloride to precipitate the rhodium. He later reacted a rose-red precipitate with zinc to release the free metal. Around the same time, Smithson Tennant analyzed a dark, insoluble residue left from dissolving platinum. He identified two new elements in that residue: iridium and osmium. He named iridium after Iris, the Greek goddess of the rainbow. He chose this because the metal's salts are strongly colored.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color

Iridium is famous for being the most corrosion-resistant metal known. This means it is not attacked by acids, even aqua regia. Because of this strength, it is often used as a hardening agent for platinum alloys. Rhodium is also very durable and has high reflectance. It is used in jewelry to provide a shiny finish. Unlike many other metals, rhodium does not normally form an oxide when heated. It is also insoluble in nitric acid. These properties make both metals highly valuable and useful in specialized science and industry.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color

Meitnerium is the most different member of the group because it is synthetic. This means it is made by humans in a lab rather than found in nature. A German research team led by Peter Armbruster and Gottfried Münzenberg first synthesized it on August 29, 1982. They worked at the Institute for Heavy Ion Research in Darmstadt. The team bombarded a target of bismuth-209 with accelerated iron-58 nuclei. This process detected a single atom of the isotope meitnerium-266. This discovery was confirmed three years later in the Soviet Union. All known isotopes of meitnerium are radioactive and have short half-lives. Because of this, it has not been isolated in pure form.

Wollaston William Hyde Jackson color
Wollaston William Hyde Jackson color
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