Nepedia
Back to Discover
Advanced Reader
⚛️

Fullerene

physical science Maturity 11-13 Next article →

Fullerenes are a unique family of carbon allotropes. An allotrope is a different form of the same element. For a long time, scientists only knew about three forms of carbon. These were diamond, graphite, and amorphous carbon like soot.

C60 Buckyball
C60 Buckyball

Fullerenes changed this understanding by adding many new shapes to the list. These molecules consist of carbon atoms connected by single and double bonds. They form a closed or partially closed mesh of fused rings. These rings are made of five or six atoms.

C60 Molecule
C60 Molecule

This structure allows for many different shapes, including hollow spheres, ellipsoids, or tubes.

The way these molecules are built depends on the arrangement of their rings. The IUPAC defines fullerenes as polyhedral closed cages. These cages are made entirely of three-coordinate carbon atoms. This means each carbon atom is bonded to three others. The structure must have exactly 12 pentagonal faces. It also contains (n/2 - 10) hexagonal faces, where n is the number of atoms.

c60 isosurface
c60 isosurface

For example, the most famous member is C60. It is a truncated icosahedron. This shape uses 20 hexagons and 12 pentagons. The carbon atoms sit at the vertices of these polygons. The bonds follow the edges of the shapes. This specific arrangement ensures that no two pentagons share an edge.

Fullerenes can be categorized into two major families. The first family consists of closed buckyballs. These are the sphere-like molecules.

Fullerene C70
Fullerene C70

The second family includes cylindrical carbon nanotubes, also called buckytubes. These tubes are often only a few nanometers wide. However, they can reach lengths of several millimeters.

Kohlenstoffnanoroehre Animation
Kohlenstoffnanoroehre Animation

Some structures exist between these two classes. These are called carbon nanobuds. They are nanotubes capped by hemispherical meshes. There are also nested fullerenes called buckyons or carbon nano-onions. These consist of one closed fullerene inside another.

The history of fullerenes is a story of predictions and accidental discoveries. In 1965, scientists mentioned the icosahedral cage as a possible structure. In 1970, Eiji Osawa predicted their existence. He noticed a molecule called corannulene looked like a piece of a football. He hypothesized a full ball shape could exist. R. W. Henson also proposed the structure in 1970. However, the evidence was weak, so the scientific community was skeptical.

C20 Fullerene
C20 Fullerene

It was not officially acknowledged until 1999. In 1985, Harold Kroto and his team finally discovered them. They were working with James R. Heath, Sean O'Brien, Robert Curl, and Richard Smalley. They found the molecules in sooty residue created by vaporizing carbon in helium.

This discovery had a massive impact on science. Kroto, Curl, and Smalley won the 1996 Nobel Prize in Chemistry.

C60 Fullerene solution
C60 Fullerene solution

Fullerenes are found in many unexpected places. They appear in sooty flames and lightning discharges. In 1992, they were found in shungite minerals in Russia.

C60 SEM
C60 SEM

Scientists even found them in outer space. In 2010, NASA's Spitzer infrared telescope saw C60 and C70 in a dust cloud. This cloud is 6,500 light years away from Earth. In 2019, the Hubble Space Telescope detected ionized C60 in the space between stars. Some astronomers suggest these "spaceballs" might have provided seeds for life on Earth.

Carbon nanotubes have extraordinary physical properties. They possess high tensile strength and high electrical conductivity. They also have high heat conductivity and high ductility.

Carbon nanotube zigzag povray cropped
Carbon nanotube zigzag povray cropped

Because they are cylindrical and planar, they have relative chemical inactivity. This means their atoms are not easily displaced. Scientists have proposed many uses for these materials. In 2007, researchers worked on paper batteries using nanotubes. In the field of space technology, people suggest using carbon cables for a space elevator.

Fullerenes connect to many different scientific fields. They are studied in materials science, electronics, and nanotechnology. Chemists also study heterofullerenes. These are structures where some carbon atoms are replaced by other elements like boron, nitrogen, or oxygen.

C60 Fullerene solution
C60 Fullerene solution

This expands the entire class of fullerene compounds. The name "buckminsterfullerene" honors the architect Buckminster Fuller. His geodesic domes look similar to these carbon cages. By studying these molecules, we learn how carbon can organize itself in the universe.

666 words

Where will your curiosity go next?

Keep exploring at your chosen reading level.

🖼️ Images & Media (12)
File:C60 Molecule.svg
C60 Molecule.svg
File:C20 Fullerene.png
C20 Fullerene.png
File:Carbon nanotube zigzag povray cropped.PNG
Carbon nanotube zigzag povray cropped.PNG
File:C60-Fulleren-kristallin.JPG
C60-Fulleren-kristallin.JPG
File:Fullerene c540.png
Fullerene c540.png
File:c60 isosurface.png
c60 isosurface.png
File:C60 Buckyball.gif
C60 Buckyball.gif
File:Fullerene_C70.png
Fullerene_C70.png
File:Kohlenstoffnanoroehre Animation.gif
Kohlenstoffnanoroehre Animation.gif
File:C60 SEM.jpg
C60 SEM.jpg
File:C60 Fullerene solution.jpg
C60 Fullerene solution.jpg
File:Carbon 60 Olive Oil Solution.JPG
Carbon 60 Olive Oil Solution.JPG
More to explore

What is Nepedia?

A free, ad-free encyclopedia for children. Every article is written at five reading levels, so the same page works for a five-year-old and a fifteen-year-old — use the level switcher above to see this one change. No account needed to read.