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Explosive

physical science Maturity 7-9 Vital Level 3 Next article →

An explosive is a reactive substance containing a massive amount of potential energy. When this energy is released suddenly, it produces an explosion. This event typically generates light, heat, sound, and intense pressure.

GHS-pictogram-explos
GHS-pictogram-explos

Scientists define an explosive charge as a measured quantity of such material. These substances can consist of a single ingredient or a mixture of different chemicals. The stored energy can come from several different sources. Chemical energy is found in substances like nitroglycerin or even grain dust. Pressurized gas can be stored in cylinders, aerosol cans, or through boiling liquid expanding vapor explosions. There is also nuclear energy, which is found in fissile isotopes such as uranium-235 and plutonium-239.

Chemical explosives work through a very rapid and spontaneous reaction. This process is driven by a large exothermic change, which means it releases heat. It also involves a large positive entropy change as reactants turn into products. Most commercial explosives are organic compounds containing specific chemical groups like –NO2, –ONO2, or –NHNO2. When these materials react, they release gases such as carbon monoxide, carbon dioxide, and nitrogen gas. These gases are very stable because they contain strong double and triple bonds. The energy released during the reaction is nearly 1 MJ/mole. Traditional chemical explosives often rely on the rapid oxidation of carbon and hydrogen. Nitrates in the mixture usually provide the oxygen needed to burn these fuels. Sometimes, a sensitizer like powdered aluminum is added to increase the detonation energy.

Explosives are categorized by their velocity, or how fast they expand. Materials that deflagrate are known as low explosives. In deflagration, a flame front moves through the material at subsonic speeds. This means the reaction moves slower than the speed of sound. Low explosives are often used as propellants, such as gunpowder in a bullet casing. Under high pressure or temperature, they can produce effects similar to a detonation. In contrast, high explosives detonate. This means an explosive shock front passes through the material at supersonic speeds. The detonation velocity is much higher than the speed of sound in the material. For example, TNT has a detonation rate of about 6,900 meters per second. C-4 is even faster, with a rate of approximately 8,000 meters per second.

Another way to classify explosives is by their sensitivity to stimuli. Primary explosives are extremely sensitive to heat, friction, impact, or static electricity. They require only a very small amount of energy to initiate. Some substances, like nitrogen triiodide, are so sensitive they cannot be handled safely. Nitrogen triiodide can even be detonated by exposure to alpha radiation. Because of this high sensitivity, primary explosives are used in small amounts within detonators. They act as a trigger for larger, more stable charges. Secondary explosives, such as TNT or RDX, are much less sensitive. They require substantially more energy to start a reaction. This makes them safer to handle and store in large quantities. Tertiary explosives, or blasting agents, are even more stable. They are so insensitive that they cannot be reliably detonated by primary explosives alone. Instead, they require an intermediate booster made of secondary explosives. These are commonly used in large-scale mining and construction.

UN transport pictogram - 1
UN transport pictogram - 1

The history of chemical explosives is closely tied to the history of gunpowder. Ancient times saw the use of thermal weapons like Greek fire. Taoist alchemists in China created the first gunpowder using coal, saltpeter, and sulfur. This was the first form of chemical explosive used in warfare, appearing around 1161. Early military explosives included bamboo firecrackers fired from tubes. In 1847, nitroglycerin was developed as the first explosive stronger than black powder. However, nitroglycerin is a liquid and is highly unstable. By 1863, it was replaced by safer materials like nitrocellulose and trinitrotoluene (TNT). In 1867, smokeless powder and dynamite were introduced. During World War I, TNT became common in artillery shells. World War II saw the use of even newer explosives.

Modern technology has introduced even more powerful and specialized materials. Modern weapons often use explosives like C-4 or pentaerythritol tetranitrate (PETN). These materials are useful because they are malleable and waterproof. However, they can still catch fire if they react with certain metals. It is important to distinguish between explosives and simple combustible materials. Many substances like gases, powders, or volatile liquids are only flammable under normal conditions. They may only become explosive if they are dispersed in an airborne cloud or confined in a space. This distinction is vital for safety and engineering.

Understanding explosives connects to many fields of science and industry. The study of these reactions helps engineers design safer mining tools. It also helps chemists create more stable materials for transport. The way energy is stored in chemical bonds is a central concept in thermodynamics. By studying how substances decompose, scientists can improve storage safety. Whether used in a small firework or a large construction site, explosives rely on the predictable release of stored energy. This energy can be managed through careful classification of velocity and sensitivity. This allows humans to use these powerful reactions for many different purposes.

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