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Cubic crystal system

physical science Maturity 11-13 Next article →

Crystals are built from tiny building blocks called unit cells. In the cubic crystal system, these blocks are shaped like cubes.

Cubic
Cubic

This system is very important because it is one of the simplest ways atoms can arrange themselves. Many minerals and metals use these shapes to stay strong and stable. Understanding these cubes helps scientists learn how different materials behave. It is like finding the basic patterns in a giant Lego set.

Kubisches Kristallsystem
Kubisches Kristallsystem

There are three main ways atoms pack into these cubic shapes. The first is primitive cubic, which has one atom at each corner.

Cubic
Cubic

This way is rare in nature and is only found in polonium. The second is body-centered cubic, or bcc. This has atoms at the corners plus one right in the center.

Cubic-body-centered
Cubic-body-centered

The third is face-centered cubic, or fcc. This has atoms at the corners and one in the middle of each flat face.

Cubic-face-centered
Cubic-face-centered

These different patterns change how much space the atoms take up.

Scientists use special numbers to describe these patterns. The atomic packing factor, or APF, tells us how much space is filled by atoms. The primitive cubic shape has a low APF of about 0.524. The body-centered cubic shape is denser with an APF of about 0.680. The face-centered cubic shape is the tightest with an APF of about 0.740.

FCC primative-cubic cells
FCC primative-cubic cells

We also look at the coordination number. This is the number of nearest neighbors around a central atom. In a bcc structure, the number is 8. In an fcc structure, the number is 12.

Many common things around us use these cubic patterns. Metals like iron, chromium, and tungsten use the body-centered cubic shape.

BCC primitive
BCC primitive

Other metals like gold, silver, and copper use the face-centered cubic shape. Some special structures use two different kinds of atoms together. For example, the rock-salt structure is used by sodium chloride, which is common table salt.

NaCl octahedra in crystal
NaCl octahedra in crystal

In this structure, the atoms form a pattern like a 3D checkerboard. Another pattern is the caesium chloride structure, where two different cubes overlap.

Cesium Chloride
Cesium Chloride

These patterns help us understand the world of chemistry. For instance, the diamond cubic structure is found in carbon and silicon. Even though it is called cubic, it is not a simple lattice like the others. Some structures, like the zincblende structure, are named after specific minerals.

Sphalerite-unit-cell-depth-fade-3D-balls
Sphalerite-unit-cell-depth-fade-3D-balls

This structure is used by many compound semiconductors. By studying these tiny cubes, we can learn how to make new technology. It shows us that even the smallest things follow very organized rules.

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🖼️ Images & Media (26)
File:NaCl octahedra in crystal.svg
NaCl octahedra in crystal.svg
File:CsCl crystal.svg
CsCl crystal.svg
File:Monoclinic.svg
Monoclinic.svg
File:Cubic.svg
Cubic.svg
File:Orthorhombic.svg
Orthorhombic.svg
File:Tetragonal.svg
Tetragonal.svg
File:Rhombohedral.svg
Rhombohedral.svg
File:Triclinic.svg
Triclinic.svg
File:FCC primative-cubic cells.svg
FCC primative-cubic cells.svg
File:Visualisation diamond cubic.svg
Visualisation diamond cubic.svg
File:2d hp.svg
2d hp.svg
File:2d op rectangular.svg
2d op rectangular.svg

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