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Chalcedony

earth science Maturity 7-9 Next article →

Chalcedony is a fascinating cryptocrystalline form of silica. This means it is made of extremely fine intergrowths of minerals. It is composed of quartz and a mineral called moganite. While both are silica minerals, they have different structures. Quartz has a trigonal crystal structure. Moganite has a monoclinic structure. This mixture gives chalcedony a characteristic waxy luster.

Mogánite-798422
Mogánite-798422

The mineral is often semitransparent or translucent. It can appear in many colors. Common shades include white, gray, or grayish-blue. You might also see browns ranging from pale to nearly black.

carnelian sard (mineral specimen)
carnelian sard (mineral specimen)

Many famous semi-precious gemstones are actually varieties of chalcedony. Each type is defined by its unique colors or patterns. Agate is a fibrous, banded variety with many patterns.

Quartz - Agateplate, redbrown-white
Quartz - Agateplate, redbrown-white

Iris agate shows iridescence when light shines through it. Landscape agate uses mineral impurities to look like scenery. Carnelian is a reddish-brown variety that can range from pale orange to almost black.

carnelian sard (mineral specimen)
carnelian sard (mineral specimen)

Sard is a similar variety, but it is brown rather than red. Onyx is a type of agate with black and white banding.

Agate-Quartz-49959
Agate-Quartz-49959

Sardonyx features banding in brown, orange, red, and white.

Other varieties get their colors from specific chemical elements. Chrysoprase is a green variety colored by nickel oxide.

Chryzopras Polsko
Chryzopras Polsko

If the blue color is very rich, it is sometimes called blue chrysoprase. This blue color comes from copper. Heliotrope, also known as bloodstone, is green with red iron oxide inclusions.

Quarz - Heliotrop (Blutjaspis)
Quarz - Heliotrop (Blutjaspis)

These red spots look like drops of blood. Moss agate contains green, filament-like inclusions. These look like moss or blue cheese.

mossagate.pebble.750pix
mossagate.pebble.750pix

Chrome chalcedony is green due to chromium compounds. In Zimbabwe, it is known as mtorolite. In Bolivia, it is called chiquitanita.

Humans have used chalcedony for thousands of years. As early as 32,000 years ago, people in Central Australia made tools from it. They used flakes from stone found in distant quarries. In prehistoric times, people used ground chalcedony for cave paintings. They mixed the powder with water and animal fat or tree resin.

ChalcedonyKnifeNPS
ChalcedonyKnifeNPS

During the Bronze Age, chalcedony was used in the Mediterranean. For example, Minoan seals date to around 1800 BC at the Palace of Knossos. In the 1st century, people in Afghanistan made fine objects from it.

Titus cameo
Titus cameo

These items often showed Greco-Roman influence.

The history of the name chalcedony is quite interesting. It likely comes from the ancient Greek town of Chalkedon. This town is now the Kadıköy district of Istanbul. However, some dictionaries say this connection is doubtful. The name also appears in the Bible in the Book of Revelation. It is used as a term for a gem, but it appears nowhere else in the text. This makes it hard to know if it refers to modern chalcedony.

Titus cameo
Titus cameo

In Greenland, a light blue variety is called "ice-blue." This name comes from its ice-like color.

Iceblue-all2 hg
Iceblue-all2 hg

In the 19th century, Idar-Oberstein in Germany became a major center for processing. They worked mostly on agates from Latin America, especially Brazil. Ships used these agate nodules as ballast. This made the transport very cheap. The workers in Idar-Oberstein had great knowledge of chemistry. They used secret processes to dye agates into any color. Each mill used four or five red sandstone grindstones. Two men usually worked together at each stone.

Sumin chalcedony mouse
Sumin chalcedony mouse

There is a scientific reason why chalcedony behaves differently than quartz. Even though they are chemically identical, chalcedony is more soluble in water. This is especially true at low temperatures. Scientists believe this happens because of the moganite component. Small crystal sizes and defects from Brazil twinning may also cause this.

Mogánite-798422
Mogánite-798422

At 25 degrees Celsius, chalcedony has a solubility of 4.92 mg/L. In comparison, quartz only has a solubility of 2.64 mg/L. This shows how small structural changes change how a mineral interacts with its environment.

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🖼️ Images & Media (13)
File:Quartz - Agateplate, redbrown-white.jpg
Quartz - Agateplate, redbrown-white.jpg
File:carnelian sard (mineral specimen).jpg
carnelian sard (mineral specimen).jpg
File:Chryzopras Polsko.jpg
Chryzopras Polsko.jpg
File:Agate-180670.jpg
Agate-180670.jpg
File:Quarz - Heliotrop (Blutjaspis).JPG
Quarz - Heliotrop (Blutjaspis).JPG
File:mossagate.pebble.750pix.jpg
mossagate.pebble.750pix.jpg
File:Mtorolite zimbabwe trimmed.jpg
Mtorolite zimbabwe trimmed.jpg
File:Agate-Quartz-49959.jpg
Agate-Quartz-49959.jpg
File:Iceblue-all2_hg.jpg
Iceblue-all2_hg.jpg
File:Titus cameo.jpg
Titus cameo.jpg
File:ChalcedonyKnifeNPS.jpg
ChalcedonyKnifeNPS.jpg
File:Mogánite-798422.jpg
Mogánite-798422.jpg

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