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Amalgam (chemistry)

physical science Maturity 9-11 Next article →

An amalgam is a special kind of alloy made by mixing mercury with another metal. Depending on how much mercury is used, the mixture can be a liquid, a soft paste, or a solid.

Amalgam-200675
Amalgam-200675

These alloys form through metallic bonding. This happens when electrostatic forces bind metal ions together into a crystal lattice structure. Many different metals can form amalgams with mercury. However, some metals like iron, platinum, tungsten, and tantalum are notable exceptions. Because mercury does not mix with iron, people once used iron flasks to carry it.

Amalgamprobe
Amalgamprobe

Making an amalgam is a fascinating thing that happens through chemical reactions. When metals touch mercury at room temperature, many will readily dissolve into it. This ability to dissolve, called solubility, actually increases as the temperature goes up. Some elements like indium, thallium, cadmium, and cesium dissolve very easily. The reaction that forms these amalgams is typically exothermic, which means it gives off heat. The final shape of the amalgam depends on the amount of mercury used. If there is a lot of mercury, it might stay liquid.

Filling
Filling

Humans have used amalgams for a very long time in many different ways. In China, people used amalgam gilding to coat silver as early as the third to first centuries BC. This was a way to make surfaces look like precious metal. In the 16th century, glassmakers on the island of Murano in Italy used tin amalgam. They created reflective mirror coatings by sliding glass over tin flooded with mercury. This method was the main way to make mirrors until around 1900.

Amalgam-200675
Amalgam-200675

Amalgams are also very important in the worlds of medicine and mining. Dentists use dental amalgams to fill cavities in teeth. These fillings are made by mixing mercury with metals like silver, copper, indium, tin, and zinc. The mixture stays soft for a short time so the dentist can pack it into the tooth. Then, it turns into a hard compound.

Filling
Filling

In mining, mercury helps people find tiny specks of gold. Miners wash crushed ore over copper sheets coated in mercury. The fine gold sticks to the mercury to form an amalgam.

Grabill - Clean Up day at the Deadwood Terra Gold Stamp Mill
Grabill - Clean Up day at the Deadwood Terra Gold Stamp Mill

Even though amalgams are useful, mercury is a harmful toxin that needs special care. Because it can cause pollution, many modern processes have changed. In the mining industry, mercury amalgamation has been replaced by other methods in developed nations. In dentistry, the EU prohibited using amalgam for children under 15 or for pregnant women in 2018. The FDA in the US also recommends against its use for certain high-risk groups. We must be careful because even small amounts of mercury can damage the environment.

Grabill - Clean Up day at the Deadwood Terra Gold Stamp Mill
Grabill - Clean Up day at the Deadwood Terra Gold Stamp Mill
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Filling.jpg
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Grabill - Clean Up day at the Deadwood...
File:Amalgamprobe.jpg
Amalgamprobe.jpg
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