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Allotropes of oxygen

physical science Maturity 11-13 Next article →

Oxygen is a very special element that can take many different forms. Scientists call these different forms allotropes.

Triplett-Sauerstoff
Triplett-Sauerstoff

The most famous form is called dioxygen. It is also known as molecular oxygen or triplet oxygen. This gas makes up about 21% of the air around us. Living things use this oxygen to get energy through cellular respiration. It is a colorless gas that we cannot see.

Oxygen changes depending on how its atoms are put together. In dioxygen, two oxygen atoms bond together. This form has two unpaired electrons. Because of these electrons, liquid oxygen is actually attracted to magnets. Another form is called ozone, which has three oxygen atoms.

Ozone is a pale blue gas. It is very reactive and can be unstable. In the high atmosphere, ozone acts as a shield. It protects all life from the sun's harmful ultraviolet radiation.

People have been studying these forms for a long time. Christian Friedrich Schönbein named ozone in 1840. He used an ancient Greek word that means "to smell." Scientists also suspected a form called tetraoxygen existed since the early 1900s.

A team led by Fulvio Cacace at the University of Rome finally identified it in 2001. They found it was made of two molecules held together loosely. This discovery helped us understand how oxygen behaves in different states.

There are many specific facts about these different types of oxygen. Atomic oxygen is made of single atoms instead of pairs. It is very reactive and bonds to things quickly. On Earth, it only lasts for a very short time. However, 96% of oxygen in low Earth orbit is atomic oxygen.

Scientists have even detected atomic oxygen on Mars using tools like the Viking and Mariner probes. Other forms like singlet oxygen have different properties because of their electron shells.

Oxygen can even behave like a metal under the right conditions. There are six different phases of solid oxygen. One phase is a dark-red cluster called octaoxygen.

If you apply a huge pressure of 96 GPa, oxygen becomes metallic. In this state, it can become a superconductor at very low temperatures. This means it can carry electricity without losing energy. It is amazing to see how one element can act so differently.

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