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Siliceous ooze

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Siliceous ooze is a specific type of biogenic pelagic sediment found on the deep ocean floor. It is a vital component of the marine environment, though it is relatively rare. These oozes cover approximately 15% of the entire ocean floor. To be scientifically classified as an ooze, a sediment must consist of at least 30% skeletal remains from pelagic microorganisms. These are organisms that live in the open water column rather than on the sea floor.

Marinesediments
Marinesediments

Most siliceous oozes are composed of the silica-based skeletons of microscopic creatures. The two most important groups are diatoms and radiolarians. These organisms use opal silica, which has the chemical formula SiO2·nH2O, to build their protective structures. This distinguishes them from calcareous oozes, which are made of calcium carbonate skeletons.

The creation of these skeletons happens through a complex biological process called biomineralization. Diatoms and radiolarians must extract silica from the seawater in the form of silicic acid, or Si(OH)4. Once the organism takes in these molecules, they are moved into its cytoplasm. Specialized proteins called silicon transporters manage this movement. These proteins are essential because they prevent the silica from hardening too early during transport. The silicic acid is then moved into silica deposition vesicles. Inside these tiny containers, the molecules are transformed into solid opal silica.

Once these organisms die, their remains begin a long journey to the seafloor. This process is influenced by the opal silica saturation state of the ocean. As opal particles sink, they dissolve, which actually increases the silica concentration at greater depths. This makes the formation of new opal silica thermodynamically unfavorable in deep water. To reach the bottom, the silica must sink faster than it dissolves. One way this happens is through re-packaging. This occurs when opal particles are encased in larger pieces of organic matter, such as fecal pellets. This organic coating acts like a protective shield against dissolution.

Radiolarian - Podocyrtis ampla (29391267424)
Radiolarian - Podocyrtis ampla (29391267424)

This packaging allows more material to reach the seafloor successfully.

Siliceous oozes are generally categorized into two distinct types based on their biological makeup. Diatomaceous oozes are predominantly composed of diatom skeletons. These are typically found in higher latitudes near continental margins. Examples include the North Pacific Ocean and the Southern Ocean.

Phytoplankton bloom off Argentina - November 9, 2013
Phytoplankton bloom off Argentina - November 9, 2013

In contrast, radiolarian oozes consist mostly of radiolarian skeletons. These are primarily located in tropical equatorial and subtropical regions. You can find these in the subtropical Pacific and the Indian Ocean. The Southern Ocean is unique because it features a massive, contiguous band of siliceous ooze. This is caused by the constant upwelling of deep water, which provides the nutrients needed for massive biological growth.

The accumulation of these sediments happens over very long timescales. In the open ocean, the rate is roughly 0.01 mol Si m−2 yr−1. However, the Southern Ocean sees much faster accumulation at 0.1 mol Si m−2 yr−1. In these productive waters, it can take 20 to 50 years for a skeleton to sink to the bottom.

PS2492-2 0-1298 sediment-core hg
PS2492-2 0-1298 sediment-core hg

Once the ooze is deposited, it can undergo a transformation called diagenesis. If the silica accumulates faster than it can dissolve, it may turn into a hard rock called marine chert. This recrystallization and cementation process can take tens of millions of years. When chert forms, it permanently removes silica from the oceanic cycle.

Siliceous ooze plays a massive role in the global silica cycle and carbon sequestration. The deposition of this ooze is the largest long-term sink for silica in the ocean. On average, only 4% of the opal silica produced at the surface reaches the seafloor. The other 96% is recycled back into the water column. On a biological timescale, a single molecule of silica might be recycled 25 times. Each molecule stays in the cycle for about 400 years before it is finally buried.

This cycle is balanced by the weathering of silicates on land and river inputs.

Diatoms are also crucial for managing atmospheric carbon dioxide through the biological pump. As primary producers, they use photosynthesis to convert carbon dioxide into organic carbon. Because diatoms are relatively large, they can absorb significant amounts of carbon. Their heavy opal silica shells also act as ballast, helping them sink rapidly to the deep sea. This carries carbon away from the surface. Scientists have even conducted iron fertilization experiments to see if increasing nutrients can trigger diatom blooms. The goal is to see if more diatoms can increase the rate of carbon sequestration in the deep ocean.

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🖼️ Images & Media (5)
File:Centric diatom (3075277530).jpg
Centric diatom (3075277530).jpg
File:Radiolarian - Podocyrtis ampla (29391267424).jpg
Radiolarian - Podocyrtis ampla (29391267424).jpg
File:Marinesediments.jpg
Marinesediments.jpg
File:Phytoplankton bloom off Argentina - November 9, 2013.jpg
Phytoplankton bloom off Argentina -...
File:PS2492-2 0-1298 sediment-core hg.jpg
PS2492-2 0-1298 sediment-core hg.jpg
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