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Protactinium

physical science Maturity 11-13 Next article →

Protactinium is a rare and dense chemical element. It is represented by the symbol Pa and has the atomic number 91. As an actinide metal, it appears as a silvery-gray substance. It is highly radioactive and reacts quickly with oxygen, water vapor, and inorganic acids. Because of its extreme scarcity, high radioactivity, and high toxicity, humans do not use it for commercial products. Instead, it is used almost exclusively for scientific research. Most of the protactinium used today is extracted from spent nuclear fuel.

Uraninite-39029
Uraninite-39029

The behavior of protactinium is defined by its various isotopes. An isotope is a specific version of an element with a different number of neutrons. The most stable and abundant version is protactinium-231. This isotope makes up nearly 100% of naturally occurring protactinium. It has a half-life of 32,760 years, which is the time it takes for half of the atoms to decay. This isotope is part of the decay chain of uranium-235. Other isotopes, such as 234Pa, are much shorter-lived. They are produced during the decay of uranium-238. There are thirty known isotopes of protactinium, ranging from 210Pa to 239Pa. Most of these have extremely short half-lives, some lasting less than 1.8 seconds.

PaCl5
PaCl5

In nuclear reactors, protactinium plays a complex role. It is often an undesired intermediate product. For example, when thorium-232 undergoes neutron irradiation, it can produce protactinium-233. This isotope has a half-life of about 27 days. It is considered a "neutron poison" because it has a high cross section for neutron capture. This means it can absorb neutrons that are needed to keep the reactor efficient. To prevent this, scientists sometimes extract protactinium-233 from the active zone of thorium molten salt reactors. They use columns of molten bismuth containing dissolved lithium to do this. The lithium reduces the protactinium salts into metal, which is then removed from the cycle.

Uranocene-3D-balls
Uranocene-3D-balls

The history of discovering protactinium involves many famous scientists and long periods of searching. In 1871, Dmitri Mendeleev predicted its existence. He noticed a gap in his periodic table between thorium and uranium.

Periodensystem Mendelejews
Periodensystem Mendelejews

For a long time, chemists thought the missing element was "eka-tantalum," an element with properties similar to tantalum. This made the search very difficult. In 1900, William Crookes isolated a radioactive material from uranium. He called it "uranium X" because he could not yet prove it was a new element. In 1913, Kazimierz Fajans and Oswald Helmuth Göhring identified the isotope 234mPa. They named it "brevium" because that specific isotope had a very short half-life of only 1.16 minutes.

Later, more stable versions were found by different researchers. Lise Meitner and Otto Hahn discovered the isotope 231Pa between 1917 and 1918. John Arnold Cranston also discovered a stable isotope in 1915, but he delayed his announcement due to the First World War. Meitner proposed the name "protactinium," which means "precursor of actinium." This name describes how the element decays into actinium. The IUPAC officially confirmed this name and credited Hahn and Meitner in 1949. In 1934, Aristid von Grosse successfully isolated elemental protactinium from 0.1 milligrams of protactinium oxide.

PaCl5
PaCl5

Protactinium is incredibly rare in the natural world. In the Earth's crust, concentrations are typically only a few parts per trillion. However, it can reach up to a few parts per million in certain uraninite ore deposits. For instance, some ores from the Democratic Republic of the Congo contain about 3 parts per million of protactinium-231. It is also found in water, though at much lower levels of about one part per trillion. Scientists have found that there is about 500 times more protactinium in sandy soil than in the water surrounding it. In certain types of clay, like bentonite, the ratio can be as high as 2,000 to 1.

Uraninite-39029
Uraninite-39029

Ocean science uses protactinium to study the history of our planet. By analyzing the concentrations of uranium, thorium, and protactinium isotopes in water and minerals, scientists can perform radiometric dating. This method allows them to date sediments that are up to 175,000 years old. This data helps researchers create models of various geological processes. It also helps them understand the geography of ancient oceans. Because protactinium-231 is part of the uranium-235 decay chain, it acts as a vital tool for mapping how the Earth has changed over vast amounts of time.

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File:Periodensystem_Mendelejews.jpg
Periodensystem_Mendelejews.jpg
File:Uraninite-39029.jpg
Uraninite-39029.jpg
File:PaCl5.svg
PaCl5.svg
File:Uranocene-3D-balls.png
Uranocene-3D-balls.png
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