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Polyethylene terephthalate

physical science Maturity 7-9 Next article →

Polyethylene terephthalate is a widely used thermoplastic polymer resin. It belongs to the polyester family of plastics. People often use the acronym PET or PETE to describe it. It is a highly versatile material used in many industries. In 2020, the global production of PET reached 82 million tons. This makes it the fourth-most-produced polymer in the world. It follows polyethylene, polypropylene, and polyvinyl chloride in total production volume.

Polyethyleneterephthalate
Polyethyleneterephthalate

Creating PET involves a series of chemical reactions to join small units. These repeating units have the chemical formula C10H8O4. One method uses an esterification reaction between terephthalic acid and ethylene glycol. This process produces water as a byproduct. Another method uses transesterification. In this version, ethylene glycol reacts with dimethyl terephthalate. This reaction produces methanol as a byproduct.

PET by Transesterification V1
PET by Transesterification V1

Following these steps, a polycondensation reaction occurs. This reaction joins the monomers into long polymer chains. This final step also releases water as a byproduct.

PET by Polycondensation V1
PET by Polycondensation V1

PET can exist in two different physical states. The first is the amorphous state. This occurs when the molten polymer is cooled very rapidly. Amorphous PET is transparent and clear. The second state is semi-crystalline. This happens when the molten material is cooled more slowly. In this state, the material forms many small crystallized areas called spherulites. Depending on the particle size, semi-crystalline PET can look transparent or opaque and white.

Plastic bottle
Plastic bottle

History shows how this material changed the textile and packaging industries. J. R. Whinfield and James Tennant Dickson patented PET in 1941 in England. The company ICI first commercialized it in the 1940s under the brand name Terylene. The name Terylene was created by inverting parts of the words poly(eth)ylene and ter(ephthalate). Later, E. I. DuPont launched the brand Dacron. In the Soviet Union, scientists developed a version called Lavsan in 1949.

Thistle dinghy with skipper Terry Lettenmaier sailing downwind
Thistle dinghy with skipper Terry Lettenmaier sailing downwind

In 1973, Nathaniel Wyeth invented the PET bottle, which was patented by DuPont.

The uses for PET are incredibly diverse. In textiles, it is known as polyester. It is used for clothing, sportswear, and automotive upholstery. In packaging, PET is used for rigid containers like soft drink bottles. To protect beverages like beer, manufacturers use a multilayer structure. They sandwich a layer of polyvinyl alcohol or polyamide inside the PET. This helps reduce oxygen permeability.

Symbol Resin Code 1 PETE
Symbol Resin Code 1 PETE

Flexible packaging also uses biaxially oriented PET, or BoPET. This film can be aluminized to create reflective surfaces. Such films are used in thermal insulation like space blankets.

PET also serves important roles in high-tech engineering. BoPET is used in the backsheets of photovoltaic modules for solar energy. It can also serve as a substrate in thin-film solar cells. In the automotive and aeronautical sectors, PET is used for various industrial parts. A special version called PETG is popular in 3D printing. PETG is used for high-end applications, such as surgical fracture tables. The surface of PETG can even be modified to be self-cleaning.

PETG structural formula section
PETG structural formula section

Scientists measure the quality of PET using intrinsic viscosity. This is a dimensionless measurement of the polymer's molecular weight. Different applications require different levels of polymerization. For example, textile fibers usually have an intrinsic viscosity between 0.40 and 0.70. Carbonated drink bottles require a higher viscosity, between 0.78 and 0.85. Engineering plastics and monofilaments require even higher levels, ranging from 1.00 to 2.00. This precision allows PET to be customized for almost any job.

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🖼️ Images & Media (11)
File:Polyethyleneterephthalate.svg
Polyethyleneterephthalate.svg
File:Thistle dinghy with skipper Terry Lettenmaier sailing downwind.jpg
Thistle dinghy with skipper Terry...
File:PETG structural formula section.svg
PETG structural formula section.svg
File:Phthalic acid isomers.PNG
Phthalic acid isomers.PNG
File:PET by Transesterification V1.svg
PET by Transesterification V1.svg
File:PET by Polycondensation V1.svg
PET by Polycondensation V1.svg
File:Plastic bottle.jpg
Plastic bottle.jpg
File:Poly(ethylene_terephthalate)_-_Type_II_Norrish_to_acetaldehyde.png
Poly(ethylene_terephthalate)_-_Type_II_Nor...
File:Symbol Resin Code 1.svg
Symbol Resin Code 1.svg
File:Symbol Resin Code 1 PETE.svg
Symbol Resin Code 1 PETE.svg
File:Symbol Resin Code 01 PET.svg
Symbol Resin Code 01 PET.svg
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