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Pentlandite

earth science Maturity 7-9 Next article →

Pentlandite is a vital iron–nickel sulfide mineral used to find nickel.

Pentlandite in pyrrhotite labelled, Sudbury
Pentlandite in pyrrhotite labelled, Sudbury

It is one of the most important sources of mined nickel on Earth. This mineral is defined by its chemical formula, which usually shows a 1:1 ratio of nickel to iron. It also contains small amounts of cobalt by weight. While it can form isometric crystals, it is usually found in massive, granular aggregates. It has a yellowish bronze color and a metallic luster.

This mineral is brittle, with a hardness of 3.5 to 4 and a specific gravity between 4.6 and 5.0. It is also non-magnetic.

To understand how pentlandite forms, we must look at how molten rocks behave. It typically forms during the cooling of a sulfide melt. These melts usually develop from the evolution of a silicate melt. Nickel is a chalcophile element, meaning it has a preference for sulfide phases. In melts that are sulfide undersaturated, nickel replaces other metals in minerals like olivine. However, in sulfide saturated melts, nickel partitions strongly into the sulfide phase.

PentlanditeTS
PentlanditeTS

This behavior is why nickel-bearing sulfides are mostly found in mafic and ultramafic melts.

The cooling process follows a specific sequence of stages. Above 1100 °C, only one sulfide melt exists. When the temperature drops to 1000 °C, a solid called monosulfide solid solution, or MSS, forms. This MSS consists mostly of iron with small amounts of nickel and copper. As the temperature continues to fall, the MSS becomes unstable. It eventually decomposes into a mixture of pentlandite and pyrrhotite. Sometimes, a separate copper-rich liquid forms, which later becomes chalcopyrite.

PentlanditeTS
PentlanditeTS

Pentlandite belongs to a group of rare minerals with similar structures. In the pentlandite group, the chemical formula is written as XY8(S, Se)8. In these minerals, silver, manganese, cadmium, or lead often replace the X position. Copper usually takes the place of the Y position. Iron, nickel, and cobalt can occupy either the X or Y positions. This group includes minerals like argentopentlandite, cobalt pentlandite, and geffroyite.

PentlanditeTS
PentlanditeTS

Identifying pentlandite in the field can be difficult because many sulfide minerals look similar. Many minerals share a brassy yellowish color and a metallic luster. To tell them apart, geologists look at the streak, which is the color left behind when the mineral is rubbed on a surface. Pentlandite leaves a light brownish bronze streak. In contrast, pyrite leaves a brownish black streak. Pyrrhotite leaves a greyish black streak, and chalcopyrite leaves a greenish black streak.

Pentlandite is also distinguished by its lack of magnetism.

History shows us how we discovered the value of this mineral. It was named after the Irish scientist Joseph Barclay Pentland. He lived from 1797 to 1873. He was the first person to note the mineral at Sudbury, Ontario.

Canadian Copper Company Copper Cliff mine
Canadian Copper Company Copper Cliff mine

This discovery helped lead to the massive mining operations seen today. One famous example is the Copper Cliff mine in Canada.

Canadian Copper Company Copper Cliff mine
Canadian Copper Company Copper Cliff mine

Pentlandite is found in many significant geological locations. It is abundant in ultramafic rocks and occasionally in mantle xenoliths. It also occurs near "black smoker" hydrothermal vents on the ocean floor. Notable deposits include the Bushveld igneous complex in South Africa and Voisey's Bay in Canada.

Pentlandite in pyrrhotite labelled, Sudbury
Pentlandite in pyrrhotite labelled, Sudbury

In the Sudbury Basin, the ore formed from sulfide melts created by a large meteorite impact. This connects the study of minerals to the study of space and planetary impacts.

Pentlandite in pyrrhotite labelled, Sudbury
Pentlandite in pyrrhotite labelled, Sudbury
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File:Pentlandite, Pyrrhotite-540342.jpg
Pentlandite, Pyrrhotite-540342.jpg
File:Pentlandite in pyrrhotite labelled, Sudbury.jpg
Pentlandite in pyrrhotite labelled, Sudbury.jpg
File:Canadian Copper Company Copper Cliff mine.png
Canadian Copper Company Copper Cliff mine.png
File:PentlanditeTS.png
PentlanditeTS.png
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