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Nitrogen cycle

earth science Maturity 9-11 Next article →

The nitrogen cycle is a complex biogeochemical cycle. It describes how nitrogen changes into many different chemical forms. These forms circulate through the atmosphere, the land, and the oceans. Nitrogen is essential for life because it helps build amino acids, nucleic acids, and chlorophyll. Most of Earth's atmosphere consists of 78% nitrogen gas. However, this gas is mostly unavailable to living things in its current state. This scarcity of usable nitrogen can limit how much life grows in an ecosystem.

Nitrogen Cycle - Reactions and Enzymes
Nitrogen Cycle - Reactions and Enzymes

The cycle begins with nitrogen fixation. This is the process of converting nitrogen gas into usable nitrates and nitrites. Lightning strikes can fix between 5 and 10 billion kg of nitrogen every year. Most fixation is actually done by specialized bacteria called diazotrophs. These bacteria use an enzyme called nitrogenase to combine nitrogen gas with hydrogen. This creates ammonia, which is then turned into organic compounds. Some bacteria, like Azotobacter, live freely in the soil. Others, like Rhizobium, live in the root nodules of legumes such as peas or alfalfa. These bacteria form a mutualistic relationship with the plant. The bacteria provide ammonia, and the plant provides carbohydrates in return.

Main marine nitrogen cycles
Main marine nitrogen cycles

Humans have added a new, massive step to this cycle through industrial processes. About 30% of all fixed nitrogen is now produced using the Haber-Bosch process. This industrial method uses very high temperatures and high pressures. It combines nitrogen gas with a hydrogen source, such as petroleum or natural gas, to create ammonia. This ammonia is used to make artificial fertilizers. While this helps grow more food, it also changes the natural balance of the planet. Human activities like fossil fuel combustion and wastewater release have dramatically altered the global cycle.

Global - Global Fertilizer and Manure, Version 1 Nitrogen Fertilizer Application (6074011960)
Global - Global Fertilizer and Manure, Version 1 Nitrogen Fertilizer Application (6074011960)

Once nitrogen is fixed, plants use a process called assimilation. Plant roots absorb nitrate or ammonium from the soil. If a plant absorbs nitrate, it must first reduce it to nitrite and then to ammonium. These ions are then used to build essential molecules like DNA. Animals and fungi obtain their nitrogen by eating these organic molecules. When organisms die or produce waste, the nitrogen enters the ammonification stage. Bacteria and fungi use enzymes like proteases to break down organic matter. This process, also called mineralization, converts organic nitrogen back into ammonia or ammonium.

Estimated nitrogen surplus across Europe 2005
Estimated nitrogen surplus across Europe 2005

Nitrification is the next critical step in the sequence. This process converts ammonium into nitrate through two distinct stages. First, bacteria like Nitrosomonas oxidize ammonium into nitrites. Next, different bacteria, such as Nitrobacter, oxidize those nitrites into nitrates. This step is vital because ammonia gas can be toxic to plants. However, nitrates are highly soluble and do not stick to soil well. This means they can easily leak into groundwater. High nitrate levels in water can cause blue-baby syndrome in infants. It can also lead to eutrophication, which causes massive algal blooms in water bodies.

Marine Nitrogen Cycle
Marine Nitrogen Cycle

The cycle completes through denitrification. This is the reduction of nitrates back into nitrogen gas. This process is carried out by bacteria like Pseudomonas under anaerobic conditions. Anaerobic means the environment lacks oxygen, such as in waterlogged soils. These bacteria use nitrate instead of oxygen during respiration. Another process called ANAMMOX, or anaerobic ammonium oxidation, also plays a role. In this reaction, ammonia and nitrite are converted into diatomic nitrogen gas and water. This specific process is a major part of how nitrogen moves in the oceans.

Nitrogen Cycle - Reactions and Enzymes
Nitrogen Cycle - Reactions and Enzymes

The marine nitrogen cycle follows similar rules but has different players. Nitrogen enters the ocean through runoff, rain, or the atmosphere. Cyanobacteria perform nitrogen fixation in the water to help phytoplankton grow. Without new nitrogen entering the marine cycle, the supply would run out in about 2,000 years. Phytoplankton release ammonia and urea into the water when they excrete waste. This organic matter eventually sinks to deeper layers of the ocean. This movement of nitrogen connects the surface waters to the deep sea, supporting life throughout the entire ocean system.

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🖼️ Images & Media (8)
File:Reactive Nitrogen Global Annual Fluxes.jpg
Reactive Nitrogen Global Annual Fluxes.jpg
File:Nitrogen Cycle - Reactions and Enzymes.svg
Nitrogen Cycle - Reactions and Enzymes.svg
File:Marine Nitrogen Cycle.jpg
Marine Nitrogen Cycle.jpg
File:Main marine nitrogen cycles.jpg
Main marine nitrogen cycles.jpg
File:Marine nitrogen cycle under future ocean acidification.jpg
Marine nitrogen cycle under future ocean...
File:Global - Global Fertilizer and Manure, Version 1 Nitrogen Fertilizer Application (6074011960).jpg
Global - Global Fertilizer and Manure,...
File:Global Global Fertilizer and Manure, Version 1 Nitrogen in Manure Production (6173194512).jpg
Global Global Fertilizer and Manure,...
File:Estimated nitrogen surplus across Europe 2005.png
Estimated nitrogen surplus across Europe 2005.png
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