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Natural hydrogen

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Natural hydrogen is a form of molecular hydrogen found within the Earth. It is often called white hydrogen, gold hydrogen, or geologic hydrogen. This distinguishes it from hydrogen produced by human industry or in laboratories. Scientists view it as a massive potential source of clean energy. Some models suggest it could meet human energy demands for thousands of years. However, extracting this gas economically remains a significant challenge. Much of the hydrogen is currently too widely dispersed to collect easily.

This gas forms through several distinct natural processes. The most common method is a process called serpentinization. This occurs when water interacts with ultramafic rocks. These rocks are rich in iron and magnesium. This reaction is especially common on the ocean floor where seawater meets the crust. Serpentinization is estimated to produce roughly 80% of the world's natural hydrogen. Other sources include the decomposition of organic matter and biological activity. There is also hydrogen from the degassing of the Earth's mantle and crust.

Another important mechanism is known as radiolysis. This is a form of natural electrolysis where water breaks apart. Current scientific models suggest radiolysis is the source of most other natural hydrogen. Hydrogen can also come from the decomposition of hydroxyl ions in minerals. In some cases, it forms through the weathering of freshly exposed rock surfaces. The solubility of this gas changes based on its environment. It is soluble in fresh water at moderate depths. However, solubility decreases at the extreme pressures found within the mantle.

Humans have encountered natural hydrogen for many decades. In the 1930s, drillers in Adelaide, Australia, found high-purity hydrogen. They viewed it as a useless byproduct of oil drilling. No efforts were made to capture the gas at that time. A different discovery happened in 1987 in Bourakébougou, Mali. A worker attempted to light a cigarette near a water well. The well unexpectedly caught fire due to seeping hydrogen. This led to the world's first economically successful hydrogen well. As of 2024, the village continues to use this resource.

Global interest in this resource is growing rapidly. In the 2020s, investments increased in the United States, France, and Australia. For a deposit to be worth working, it needs a high concentration. Typically, concentrations above 60% are considered viable. The well in Mali is even more concentrated, exceeding 95% purity. In France, the company Française De l'Énergie aims to extract hydrogen by 2027 or 2028. Recent discoveries have also been made in Tanzania and Albania in 2024.

Estimates of the total resource are quite vast. Some reports suggest there are 5 trillion tons of natural hydrogen worldwide. In 2023, researchers announced a discovery estimated between 46 million and 260 million metric tons. Even a fractional recovery of the global supply could last for hundreds of years. Scientists are looking at many different geological environments for these deposits. These include the Alps, the Pyrenees, and the Midcontinent Rift System.

Mid-continental Rift System
Mid-continental Rift System

New methods are being studied to create "orange" hydrogen. This concept involves the Midcontinent Rift System in North America. Scientists suggest pumping water down to hot, iron-rich rocks. This would trigger the production of hydrogen for extraction. This process could also involve dissolving carbon dioxide into the fluids. This would allow for simultaneous carbon sequestration through the carbonation of rocks. This creates a carbon-negative pathway for energy production. It links the study of hydrogen to the broader goal of managing atmospheric carbon.

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