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Mineral physics

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Mineral physics is the study of materials that make up the interiors of planets. It focuses on the physical properties of the substances found deep inside the Earth. This science helps researchers understand how the planet works from the inside out. By studying these materials, scientists can interpret surface measurements like gravity anomalies and geomagnetic fields. They can also understand seismic waves, which are vibrations that travel through the Earth. This information provides vital insights into plate tectonics and mantle convection. It also helps explain the geodynamo, the process that creates our magnetic field.

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To study these materials, scientists must recreate the extreme conditions of the deep Earth. They need to apply massive pressure and intense heat simultaneously. One common method is shock compression. This involves using explosions or projectiles to hit a sample. A shock wave passes through the material very quickly. This creates extremely high pressures for a very short time. However, this method is not adiabatic, meaning the pressure wave also heats the sample. Scientists must use Hugoniot curves, which are pressure-density curves, to interpret these results.

Another method is the multi-anvil press. This device uses an arrangement of eight cube-shaped tungsten carbide anvils. These anvils compress a ceramic octahedron that contains the sample and a furnace. This method was developed by Kawai and Endo in Japan. Unlike shock compression, the pressure from this press is steady. It can reach pressures of about 28 GPa, which is like being 840 km deep. It can also reach temperatures above 2300 °C. While it cannot reach the extreme pressures of a diamond cell, it can handle much larger samples. Recently, sintered diamond anvils have allowed this press to reach 90 GPa.

The diamond anvil cell, or DAC, is a small table-top device for concentrating pressure. It uses the hardness of diamonds to compress tiny, sub-millimeter samples. This device can reach pressures exceeding 3,000,000 atmospheres. That is more than 300 gigapascals, which is higher than the pressure at Earth's center. Diamonds are also transparent and have high thermal conductivity. This allows scientists to use various probes to examine the sample. Scientists can also heat the sample to thousands of degrees inside the cell.

Heating is just as important as pressure in mineral physics. Resistive heating is a common and simple method. It works by applying a voltage to a wire, which heats the wire and the surrounding area. In a diamond anvil cell, temperatures below 700 °C can be reached in air. If an argon atmosphere is used, temperatures can reach 1700 °C without damaging the diamonds. Another method is laser heating using Nd:YAG lasers. This can reach temperatures above 6000 K. However, laser heating can create large temperature gradients because it only heats the part of the sample hit by the laser.

To understand how minerals behave, scientists use an equation of state (EOS). This is a mathematical relation that shows how density varies with pressure and temperature. One example is the Mie-Grünheisen equation of state. A more realistic version is the Birch–Murnaghan equation of state. These equations are essential for deducing the properties of minerals in the deep Earth. Scientists also study other properties like viscosity, melting, and electrical conduction. They can use X-ray diffraction to find cell parameters or Raman spectroscopy to find chemical composition.

The history of this field is filled with landmark discoveries. In the early 20th century, researchers realized the outer core is fluid. They knew this because seismic waves could not propagate shear waves through it. Later, Erskine Williamson and Leason Adams studied Earth's density. They used a 500-ton hydraulic press to apply 1.2 GPa of pressure. They concluded the mantle was made of ferromagnesian silicates and the core was iron and nickel. They estimated the center's pressure at 320 GPa, which is close to modern estimates of 360 GPa.

Francis Birch made further major contributions to the field. He was a student of Percy Bridgman, who won a Nobel Prize for high-pressure research. Birch extended the Adams–Williamson equation to include temperature effects. In 1952, he published a paper that established several basic facts about Earth. He proved the mantle is mostly silicates and that a phase transition exists between the upper and lower mantle. He also confirmed that both the inner and outer core are iron alloys. Today, scientists continue this work using quantum mechanical numerical techniques to predict crystal properties.

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