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Membrane

physical science Maturity 9-11 Next article →

A membrane is a selective barrier used to separate different substances. It acts as a gatekeeper by allowing certain particles to pass through while blocking others. These particles can be molecules, ions, or other tiny pieces of matter.

Schematic of size-based membrane
Schematic of size-based membrane

Membranes are generally divided into two main groups: biological and synthetic. Biological membranes occur naturally in living things. For example, cell membranes cover cells, and nuclear membranes cover the nucleus of a cell. There are also tissue membranes, such as mucosae and serosae. Synthetic membranes are man-made for use in industrial settings or scientific laboratories.

The effectiveness of a membrane is defined by its selectivity. Selectivity is the ability of the membrane to choose what passes through. This depends heavily on the size of the membrane's pores. Pores are the tiny openings within the barrier. Particles can move through these pores via passive transport. This means they move because of pressure, concentration, or electrical gradients. Some transport can also be active.

Constant TMP and constant Flux
Constant TMP and constant Flux

Membranes can also be classified by their thickness, whether they are neutral or charged, and if they have a homogeneous or heterogeneous structure.

Scientists classify membranes into four main types based on pore size. Microfiltration (MF) is the first type. It removes particles larger than 0.08 to 2 micrometers. It operates at pressures between 7 and 100 kPa. Ultrafiltration (UF) has smaller pores, ranging from 0.005 to 2 micrometers. It can remove viruses and large molecules like proteins. Nanofiltration (NF) is often called "loose" reverse osmosis. It rejects particles smaller than 0.002 micrometers. Finally, reverse osmosis (RO) is the most precise. It removes substances at the ionic level. RO requires very high pressures, between 850 and 7000 kPa, to function.

Hollow fiber membrane wall
Hollow fiber membrane wall

The history of membranes shows how they moved from labs to the real world. People have understood the concept of membranes since the eighteenth century. However, they were rarely used outside of laboratories until after World War II. During the war, drinking water in Europe was often unsafe. Membrane filters were used to test water safety during this time. Early membranes were not widely used because they were slow and expensive. They also lacked reliability and selectivity. Large-scale use only began with microfiltration and ultrafiltration technologies. Since the 1980s, these processes have become common in large industrial plants.

To use membranes in industry, they are organized into units called modules. A module includes the membranes, the support structure, and the inlets and outlets for the fluids. One common type is the tubular module. These consist of membranes placed inside porous tubes. They are good for handling thick or high-solids liquids. Another type is the hollow fiber membrane. This consists of thousands of tiny hollow fibers bundled together in a vessel.

Cross-flow dead-end
Cross-flow dead-end

Other configurations include spiral wound membranes, which are rolled into a circle, and plate and frame modules, which use flat sheets.

Operating a membrane system requires managing several technical factors. Engineers must monitor the membrane permeability, which is how easily substances pass through. They also track the trans-membrane pressure (TMP). The TMP is the pressure difference across the membrane. The total flow of liquid through the system is called the permeate flux. One major challenge is fouling. Fouling is the accumulation of particles on the membrane surface. This can happen through pore narrowing, where material attaches to the inside of pores. It can also happen through pore blocking or the formation of a gel or cake layer on top.

Constant TMP and constant Flux
Constant TMP and constant Flux

There are two main ways to move liquid through a membrane: dead-end and cross-flow filtration. In dead-end filtration, all the liquid is pushed directly against the membrane. This causes particles to build up quickly, forming a "cake." This requires frequent cleaning. In cross-flow filtration, the liquid flows sideways across the membrane surface. Only a portion of the liquid passes through as permeate. This setup helps prevent heavy buildup and reaches a steady state. This means the flow remains constant for a longer time. This method requires less frequent cleaning than the dead-end method.

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🖼️ Images & Media (5)
File:Schematic of size-based membrane.svg
Schematic of size-based membrane.svg
File:Hollow fiber membrane wall.png
Hollow fiber membrane wall.png
File:Constant TMP and constant Flux.jpg
Constant TMP and constant Flux.jpg
File:Cross-flow_dead-end.svg
Cross-flow_dead-end.svg
File:Waste Hierarchy.png
Waste Hierarchy.png
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