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Melting

physical science Maturity 11-13 Next article →

Melting is a very important thing that happens in our world. Scientists call this process fusion. It is when a solid turns into a liquid.

Melting icecubes
Melting icecubes

This change happens because the internal energy of the solid goes up. Usually, this happens when you add heat. You can also cause melting by adding pressure. Every material has its own melting point. This is the specific temperature where the change starts. When this happens, the solid becomes a liquid.

Melting icecubes
Melting icecubes

How does it work on the inside? In a solid, the tiny molecules or ions stay in a neat order. As the temperature rises, this order begins to break down. The parts move into a less ordered state. This change is called a first-order phase transition. This means the energy changes in a specific way. Scientists measure this using enthalpy and entropy. At the melting point, the Gibbs free energy of the liquid becomes lower than the solid. This makes the liquid the more stable state for that material.

Melting icecubes
Melting icecubes

There are different ways to look at why solids break apart. One idea is called the Lindemann criterion. It says melting happens because of vibrations. The atoms in a crystal shake more and more. Eventually, the shaking becomes too much to stay in place. Another idea is the Born criterion. This says a crystal melts when it loses its rigidity. It can no longer hold its shape against a load. This is like a building becoming too weak to stand.

Melting icecubes
Melting icecubes

Some things act in very strange ways. Most liquids get thinner and flow easier as they get hotter. This is called reduced viscosity. However, elemental sulfur is different. Between 130 °C and 190 °C, sulfur actually gets thicker. There are also special cases with helium. Helium-3 and Helium-4 are very unusual. Below certain tiny temperatures, you must actually remove heat to melt them. This is the opposite of how most things work.

Melting icecubes
Melting icecubes

Sometimes, the melting point does not happen right away. A liquid can stay liquid even below its freezing point. This is called supercooling. Pure water on clean glass can do this. Even water in fine emulsions can stay liquid down to −38 °C. This happens if the liquid stays very still. Without a shake or vibration, the change might not start. You might also see a thin liquid film on a solid surface. This can help snowflakes grow or help glaciers move.

Melting icecubes
Melting icecubes
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