Nepedia
Back to Discover
Advanced Reader
💻

Lead–acid battery

technology Maturity 11-13 Next article →

A lead–acid battery is a type of rechargeable battery used to store chemical energy. It is an essential tool for modern life, particularly for starting engines in motor vehicles. These batteries are valued because they can supply high surge currents, which are large bursts of electrical power. While they have a lower energy density and are heavier than newer battery types, they remain very cost-effective.

Open Lead acid battery
Open Lead acid battery

Because they are inexpensive, they are widely used even when higher energy density is available from other designs.

The mechanism of a lead–acid battery relies on electrochemical reactions between two plates and an electrolyte. The electrolyte is a liquid solution containing about 10 percent sulfuric acid. In a fully charged state, the negative plate consists of metallic lead. The positive plate is made of lead dioxide. The electrolyte is a concentrated aqueous sulfuric acid solution, which stores most of the chemical energy.

Recharged
Recharged

When the battery discharges, the chemical energy is converted into electricity through a specific sequence of steps.

During discharge, the negative plate reacts with the sulfuric acid to produce lead(II) sulfate and hydrogen ions. This reaction releases two conduction electrons, giving the electrode a negative charge. Simultaneously, the positive plate reacts with the sulfate ions and electrons to also form lead(II) sulfate. As these reactions occur, the electrolyte loses much of its dissolved sulfuric acid and becomes primarily water.

Discharged
Discharged

Consequently, both plates become lead sulfate, and the electrolyte's density decreases. This process can be summarized as lead and lead dioxide reacting with sulfuric acid to create lead sulfate and water.

There are several distinct types of lead–acid batteries designed for different needs. Standard "flooded" batteries use a liquid electrolyte that can be inspected and topped up with pure water. To prevent leaks, some designs use a gel electrolyte instead of a liquid. These are known as valve-regulated lead–acid (VRLA) batteries. VRLA batteries include gel cell and absorbed glass mat (AGM) types. These specialized versions are common in telecommunications networks and hospital emergency systems because they can operate in many positions without leaking.

VRLA Overcharged using 12v 10A charger - Acid boiled out - case bulged and swelled
VRLA Overcharged using 12v 10A charger - Acid boiled out - case bulged and swelled

The history of this technology began with observations by Nicolas Gautherot in 1801. He noticed that wires used in electrolysis could provide a small secondary current. However, the first true rechargeable battery was invented in 1859 by French physicist Gaston Planté. His original model used two lead sheets rolled into a spiral and separated by rubber strips. In 1881, Camille Alphonse Faure improved this by creating a lead grid lattice. He pressed a lead oxide paste into the grid, which made the batteries much easier to mass-produce.

Recycling lead in a lead-acid battery recovery facility
Recycling lead in a lead-acid battery recovery facility

Lead–acid batteries have significant economic and technical specifications. In 1999, their sales accounted for 40% to 50% of the total value of batteries sold worldwide, excluding China and Russia. This represented a manufacturing market value of approximately US$15 billion. Most automotive batteries require between 6 and 12 hours to charge fully from a discharged state. They also have a relatively short cycle lifespan, usually lasting less than 500 deep cycles.

Sulfated Anode plate at right side from 12V 5aH battery
Sulfated Anode plate at right side from 12V 5aH battery

Understanding the state of charge is vital for managing these systems. One can use a hydrometer to measure the specific gravity of the electrolyte. As the battery discharges, the specific gravity falls because the acid concentration decreases.

Hydrometer (PSF)
Hydrometer (PSF)

Another method is to measure the open-circuit voltage. For a single cell, the voltage ranges from 1.8 V when fully discharged to 2.10 V when fully charged. These measurements help ensure the battery is healthy and ready to provide power for critical systems.

591 words

Where will your curiosity go next?

Keep exploring at your chosen reading level.

🖼️ Images & Media (8)
File:Discharged.gif
Discharged.gif
File:Recharged.gif
Recharged.gif
File:Hydrometer (PSF).png
Hydrometer (PSF).png
File:Open Lead acid battery.jpg
Open Lead acid battery.jpg
File:VRLA Overcharged using 12v 10A charger - Acid boiled out - case bulged and swelled.JPG
VRLA Overcharged using 12v 10A charger -...
File:Sulfated Anode plate at right side from 12V 5aH battery.jpg
Sulfated Anode plate at right side from...
File:ExplodedBattery.jpeg
ExplodedBattery.jpeg
File:Recycling lead in a lead-acid battery recovery facility.jpg
Recycling lead in a lead-acid battery...
More to explore

What is Nepedia?

A free, ad-free encyclopedia for children. Every article is written at five reading levels, so the same page works for a five-year-old and a fifteen-year-old — use the level switcher above to see this one change. No account needed to read.