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Holmium

physical science Maturity 7-9 Next article →

Holmium is a chemical element with the symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. This metal is relatively soft, silvery, and malleable, meaning it can be shaped easily. It is also fairly corrosion-resistant. However, holmium is too reactive to be found in its pure form in nature. When exposed to air, it slowly forms a yellowish oxide coating.

Holmium(III) oxide
Holmium(III) oxide

The chemical behavior of holmium is driven by its reactivity. In dry air at room temperature, the metal is relatively stable. If it is heated, however, it will burn in the air. It also reacts with water, corroding more quickly when the water is hot. This reaction forms holmium(III) hydroxide and releases hydrogen gas. In most laboratory settings, holmium exists in a trivalent oxidation state. This means its ions, known as Ho(III) ions, carry a +3 charge.

HoOxideSolution
HoOxideSolution

Holmium possesses several unique physical and magnetic properties. It is paramagnetic at standard temperature and pressure. This means it is weakly attracted to magnetic fields. However, it becomes ferromagnetic at temperatures below 20 K. Ferromagnetism is a stronger form of magnetism. Holmium has the highest magnetic moment of any naturally occurring element. It also has the highest magnetic permeability and magnetic saturation of any element. These traits make it useful for creating the strongest possible static magnets.

Holmium(III) oxide
Holmium(III) oxide

History shows that holmium was discovered through multiple paths in 1878. Swedish chemist Per Theodor Cleve isolated the element while studying erbia earth. He used a method to remove contaminants from the ore. This resulted in two new materials: a brown substance called holmia and a green one called thulia. Holmia was later identified as holmium oxide. At the same time, Jacques-Louis Soret and Marc Delafontaine discovered it through spectroscopy. Spectroscopy is the study of how light interacts with matter. They initially referred to the discovery as "Element X."

Gadolinitas
Gadolinitas

In nature, holmium is quite rare. It makes up approximately 1.4 parts per million of the Earth's crust. This level of abundance is similar to the element tungsten. It is found in minerals such as monazite and gadolinite.

Gadolinitas
Gadolinitas

Most commercial holmium is extracted from monazite sand. This process uses a technique called ion-exchange to separate it from other rare-earth metals. There are an estimated 400,000 tonnes of holmium in the crust. However, global production is only about 10 tonnes of metal per year.

Holmium has many specialized applications in science and industry. Because it has high magnetic permeability, it is used in the pole pieces of powerful magnets. This part is also called a magnetic flux concentrator. Because holmium absorbs neutrons very strongly, it is used as a "burnable poison" in nuclear reactors. This helps control the nuclear reaction. Its trivalent ions also have fluorescent properties. This allows holmium to be used in certain lasers and as a colorant in glass.

HoOxideSolution
HoOxideSolution

Specific isotopes of holmium also serve important roles. Holmium-165 is the only primordial isotope found in nature. Scientists also study synthetic isotopes like holmium-163 and holmium-166. The metastable isomer holmium-166m1 has a very long half-life of 1,133 years. It produces a rich spectrum of gamma rays. This makes it useful for calibrating gamma-ray spectrometers. Additionally, holmium oxide is used as an optical calibration standard. It is often fused into quartz cuvettes for use in spectrophotometers.

HoOxideSolution
HoOxideSolution
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