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Helium atom

physical science Maturity 5-7 Next article →

A helium atom is the fundamental unit of the chemical element helium. It is a complex system consisting of a central nucleus and two orbiting electrons. The nucleus contains two protons and, depending on the specific isotope, two neutrons. These protons and neutrons are held together by the strong force. The two electrons are bound to the nucleus by the electromagnetic force. Because it is the simplest system with more than one electron, helium is vital to physics. Scientists use it to study the concept of quantum entanglement.

Helium-term-scheme
Helium-term-scheme

To understand how helium works, physicists use a mathematical tool called the Hamiltonian. This Hamiltonian describes the atom as a three-body system. This system includes the nucleus and the two electrons. The math does not operate in our normal three-dimensional space. Instead, it functions in a 6-dimensional configuration space. Scientists try to find the atom's energy by solving the Schrödinger equation. However, unlike the hydrogen atom, there is no simple, closed-form solution for helium. Because of this complexity, researchers must use various approximations. One common method is the Hartree–Fock method, which helps estimate the ground state energy and wavefunction.

Helium-term-scheme
Helium-term-scheme

Helium exists in two distinct types of states based on how its electrons behave. These are known as parahelium and orthohelium. These names describe the different ways the electrons' spins and positions are organized. Parahelium is a singlet state. In this state, the electron spins are anti-symmetric. This means the spin wavefunction is antisymmetric, while the spatial wavefunction is symmetric. Orthohelium is a triplet state. In orthohelium, the electrons have a symmetric spin wavefunction. This requires an antisymmetric spatial wavefunction.

Helium-term-scheme
Helium-term-scheme

These different states exist because of the symmetrization postulate. This rule applies to identical fermions, which are particles like electrons. The postulate requires that the total wavefunction must be totally antisymmetric. This means if you swap the two electrons, the sign of the wavefunction must change. This rule links the spin of the electrons to their movement in space. Because of this, the choice of spin state influences the energy of the state. This explains why certain states, like the (1, 0, 0) state for orthohelium, cannot exist.

Helium-term-scheme
Helium-term-scheme

Our understanding of helium grew through important historical discoveries. In 1927, Albrecht Unsöld made the first attempt to obtain the helium spectrum using quantum mechanics. The spectrum is the specific pattern of light emitted by the atom. In 1929, Egil Hylleraas achieved a much more accurate approximation. His success was a major milestone for science. It served as one of the earliest proofs that Schrödinger's wave mechanics were valid. These researchers helped move physics from simple models to complex, multi-electron reality.

Helium-term-scheme
Helium-term-scheme

One of the hardest parts of modeling helium is electron-electron repulsion. In a simple model, we might treat each electron as if it only interacts with the nucleus. This is called the unperturbed Hamiltonian. However, the two electrons also push away from each other. This repulsion increases the energy levels of the atom. To account for this, scientists use the screening effect. One electron can partially block the nuclear charge from the other electron. This is like a shield or a screen.

Helium-term-scheme
Helium-term-scheme

Scientists use specific numbers to make their math match real-world observations. If you use a screening constant of 0.30, the math for the ground state energy aligns with experiments. The experimental ground state energy is approximately -2.903 atomic units. Without accounting for these interactions, the unperturbed energy calculation is about 30% larger than the actual data. Modern computers can now solve the many-body problem for helium with incredible precision. The ground state energy has even been computed to 40 decimal digits. This deep study of helium connects to the wider study of how all matter is structured.

Helium-term-scheme
Helium-term-scheme
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