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Heavy metals

physical science Maturity 11-13 Next article →

The term "heavy metals" is used to describe a group of metallic elements. However, the term is quite controversial among scientists. There is no single, widely accepted definition for what makes a metal "heavy."

Osmium crystals
Osmium crystals

Some scientists define them by their density, which is how much mass they have per unit of volume. Others use atomic weight or atomic number to categorize them. Because these rules vary so much, the International Union of Pure and Applied Chemistry (IUPAC) has called the term "meaningless and misleading." This is because the word "heavy" does not always describe the biological impact of the metal. Many toxicologists prefer the term "toxic metal" instead.

Different scientists use different criteria to group these elements. One common density criterion is a value greater than 5 g/cm3. Some definitions for atomic weight start at 40, while others only include elements heavier than 200, like mercury. Atomic number definitions are also used, but they are criticized for including low-density metals like rubidium. There is also a chemistry-based approach that groups metals into classes. Class A metal ions prefer to bond with oxygen. Class B ions prefer to bond with nitrogen or sulfur. Some ions are considered borderline because they show characteristics of both classes.

Heavy metals have unique physical and chemical properties. Generally, they tend to be less reactive than lighter metals. They also have fewer soluble hydroxides and sulfides. While most heavy metals are easy to distinguish from light metals, some overlap exists. For example, zinc and lead are heavy metals that share some traits with lighter metals. Conversely, lighter metals like titanium share some characteristics with heavier ones. This makes the boundary between the two groups somewhat blurry in practice.

Humans have interacted with metals since prehistory. Early people noticed the weight and malleability of metals like gold, copper, and iron. They used these properties to craft tools, weapons, and ornaments. In 1817, a German chemist named Leopold Gmelin attempted to organize the elements. He divided them into nonmetals, light metals, and heavy metals. He set specific density ranges for these groups. Light metals had densities between 0.860 and 5.0 g/cm3. Heavy metals ranged from 5.308 to 22.000 g/cm3.

Many heavy metals are actually essential for life. Certain elements are required for specific biological processes in the body. Iron and copper are needed for electron and oxygen transport. Cobalt is used for cell metabolism and complex syntheses. Zinc and manganese help regulate enzymes. Even arsenic can assist with metabolic growth in some animals. In a typical 70 kg human body, heavy metals make up about 0.01% of the total weight. This is roughly equivalent to the weight of two dried peas. Most of this weight comes from iron, zinc, and lead.

While some metals are helpful, others are highly poisonous. Elements like arsenic, cadmium, mercury, and lead are especially dangerous. These metals have a strong affinity for sulfur. In the human body, they often bind to thiol groups on enzymes. This binding inhibits the enzymes from controlling metabolic reactions. This process can lead to severe health issues. For example, mercury and lead can damage the central nervous system. Cadmium can cause degenerative bone disease. Chromium and arsenic are also known carcinogens.

Heavy metals are found in many parts of modern life despite their rarity in the Earth's crust. They are used in technologies like solar panels, mobile phones, and particle accelerators. You can also find them in cars, golf clubs, and self-cleaning ovens. However, they can also enter the environment through mining, smelting, and industrial waste. Lead was used extensively in gasoline from the 1930s until the 1970s. Even though leaded gasoline was largely phased out by 1996, soil near old roads still contains high concentrations. Understanding these metals is vital for both technology and environmental safety.

Rotating anode x-ray tube (labeled)
Rotating anode x-ray tube (labeled)
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Rotating anode x-ray tube (labeled).jpg
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