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Fermium

physical science Maturity 11-13 Next article →

Fermium is a synthetic chemical element with the symbol Fm and the atomic number 100. It belongs to a group of heavy elements known as actinides.

Enrico Fermi 1943-49
Enrico Fermi 1943-49

Fermium is unique because it is the heaviest element that can be formed through the neutron bombardment of lighter elements. This characteristic makes it the final element that scientists can prepare in macroscopic, or visible, quantities. While researchers can produce it, pure fermium metal has not yet been prepared. Because its isotopes are difficult to gather and decay quickly, fermium has no practical uses outside of basic scientific research.

Decay of Fermium-257
Decay of Fermium-257

The production of fermium relies on a process called neutron bombardment. In this mechanism, a nucleus of a lighter element absorbs neutrons to increase its mass. This can occur within a nuclear reactor, such as the 85 MW High Flux Isotope Reactor (HFIR) in Tennessee. This reactor is specifically dedicated to producing transcurium elements, which are elements with an atomic number greater than 96. During a typical campaign at Oak Ridge, scientists irradiate tens of grams of curium. This process yields milligram quantities of einsteinium and tiny picogram quantities of fermium.

Elutionskurven Fm Es Cf Bk Cm Am
Elutionskurven Fm Es Cf Bk Cm Am

Scientists have identified 20 different isotopes of fermium, which are versions of the element with different atomic weights. These weights range from 241 to 260. The isotopes vary greatly in their stability. The longest-lived isotope is fermium-257, which has a half-life of 100.5 days. Other isotopes decay much faster. For example, fermium-255 has a half-life of about 20 hours. Some isotopes are extremely unstable, lasting only a few milliseconds. This rapid decay creates what scientists call the "fermium gap." This gap exists because no accessible fermium isotopes undergo beta minus decay to become mendelevium. Instead, they undergo spontaneous fission, where the nucleus splits apart.

Decay of Fermium-257
Decay of Fermium-257

The discovery of fermium is tied to the history of nuclear physics. It was first observed in the debris of the "Ivy Mike" hydrogen bomb test on November 1, 1952.

Ivy Mike - mushroom cloud
Ivy Mike - mushroom cloud

A research team led by Albert Ghiorso at the University of California, Berkeley, identified the element. To find it, they had to process contaminated coral from the Enewetak Atoll. Because of Cold War tensions, the U.S. military kept the discovery secret until 1955. The element was named in honor of Enrico Fermi, a pioneer of nuclear physics who developed the first artificial self-sustained nuclear reactor.

Albert Ghiorso ca 1970
Albert Ghiorso ca 1970

During the mid-1950s, researchers attempted to create heavier elements using nuclear explosions. They hoped the massive neutron flux of a thermonuclear explosion would allow nuclei to capture more neutrons than a reactor could. The flux in an explosion can reach 10 neutrons per square centimeter within a microsecond. In comparison, the HFIR reactor provides about 5 neutrons per square centimeter per second. Despite these powerful tests, such as the "Hutch" test in 1969, no elements heavier than fermium were discovered.

ActinideExplosionSynthesis
ActinideExplosionSynthesis

Scientists found that the yield of these elements followed a "saw-tooth" pattern. This means that odd-numbered isotopes were produced in lower amounts because they have higher fission rates.

Collecting the products of these explosions proved to be a massive technical challenge. In atmospheric tests, the debris was spread across wide areas. Scientists tried using airplanes with paper filters to catch fallout, but this only captured a small fraction of the material. In underground tests, the debris was buried under 300 to 600 meters of rock. Even when researchers drilled shafts to help expel material, the concentration of actinides was often lower than expected. In the Hutch test, only 4.0 picograms of fermium-257 were recovered from 10 kilograms of debris. This showed that collecting these rare elements from a blast site is highly inefficient.

Fermium's chemistry is typical for the late actinides in the periodic table. It mostly exists in a +3 oxidation state, which is a way of describing its electrical charge. However, it also has an accessible +2 oxidation state. To isolate the element from other materials, scientists use ion-exchange chromatography. This process uses a cation exchanger and a solution called ammonium alpha-hydroxyisobutyrate. The different elements move through the column at different speeds, allowing researchers to separate the fermium. This specialized chemistry allows scientists to study the fundamental properties of the heaviest reachable elements.

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🖼️ Images & Media (7)
File:Ivy Mike - mushroom cloud.jpg
Ivy Mike - mushroom cloud.jpg
File:Enrico Fermi 1943-49.jpg
Enrico Fermi 1943-49.jpg
File:Albert Ghiorso ca 1970.jpg
Albert Ghiorso ca 1970.jpg
File:Decay of Fermium-257.PNG
Decay of Fermium-257.PNG
File:Elutionskurven Fm Es Cf Bk Cm Am.png
Elutionskurven Fm Es Cf Bk Cm Am.png
File:ActinideExplosionSynthesis.png
ActinideExplosionSynthesis.png
File:Fermium-Ytterbium Alloy.jpg
Fermium-Ytterbium Alloy.jpg
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