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Electrolysis

physical science Maturity 9-11 Next article →

Electrolysis is a special way to use electricity to break things apart. The name comes from Greek words that mean breakdown through electricity.

Hofmann voltameter fr
Hofmann voltameter fr

This process is very important for making things in factories. It helps us separate pure elements from natural sources like ores. To make it work, you need a few specific parts. You must have a power source that provides direct current. You also need an electrolyte, which is a liquid that carries the current. Finally, you need two electrodes to touch the liquid.

Chloralkali membrane
Chloralkali membrane

How does the process actually work? It starts when you turn on the power. This causes ions, which are tiny charged particles, to move. Positively charged ions are called cations. These cations move toward the negative electrode, which is the cathode. Negatively charged ions are called anions. These anions move toward the positive electrode, known as the anode.

P-Benzochinon
P-Benzochinon

As they move, they gain or lose electrons. This change is called reduction at the cathode and oxidation at the anode. Sometimes, this makes gases bubble out of the liquid. For example, splitting water creates hydrogen and oxygen gases.

Many scientists helped us understand this over many years. In 1800, William Nicholson and Anthony Carlisle showed how to split water. They used a device called a voltaic pile. Later, Michael Faraday studied the process with Humphry Davy. Faraday discovered two important laws of electrolysis. He also gave us the names for many parts, like anode and cathode.

Hydrochinon2
Hydrochinon2

His work helped explain how the math of electricity relates to chemistry. He even used the word "electrolysis" in 1834.

History shows that electrolysis helped us find many new elements. Humphry Davy used it to find potassium and sodium in 1807. In 1821, William Thomas Brande used it to find lithium. Other scientists used it for different discoveries too. Paul Émile Lecoq de Boisbaudran found gallium in 1875. Henri Moissan used it to find fluorine in 1886.

hall-heroult-kk-2008-12-31
hall-heroult-kk-2008-12-31

In 1886, the Hall–Héroult process was made to create aluminum. This made aluminum much cheaper to buy for everyone.

You can see electrolysis in many things you know. It is used to make metals like copper and zinc. Some people even use it for electroplating. This is when a layer of metal is put onto something else. It is also used to make things like sodium hydroxide. This happens through the electrolysis of brine, which is salty water.

Chloralkali membrane
Chloralkali membrane

By using electricity, we can turn simple liquids into many useful materials.

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🖼️ Images & Media (5)
File:Hofmann voltameter fr.svg
Hofmann voltameter fr.svg
File:P-Benzochinon.svg
P-Benzochinon.svg
File:Hydrochinon2.svg
Hydrochinon2.svg
File:Chloralkali_membrane.svg
Chloralkali_membrane.svg
File:hall-heroult-kk-2008-12-31.png
hall-heroult-kk-2008-12-31.png
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