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Dysprosium

physical science Maturity 9-11 Next article →

Dysprosium is a chemical element with the symbol Dy and atomic number 66. It is a rare-earth element within the lanthanide series. Physically, it is a soft metal with a bright, metallic silver luster.

Dysprosium
Dysprosium

Because it is quite soft, it can be machined without creating sparks, provided the metal does not overheat. However, its physical properties are very sensitive. Even tiny amounts of impurities can change how the metal behaves. This makes the production of pure dysprosium a very important task for scientists and engineers.

In nature, dysprosium is never found as a free, standalone element. Instead, it exists within various minerals. Common examples include xenotime, fergusonite, gadolinite, and monazite.

Xenotímio1
Xenotímio1

In some high-yttrium minerals, dysprosium is the most abundant of the heavy lanthanides. It makes up about 7% to 8% of the concentrate in those specific cases. The concentration of dysprosium in the Earth's crust is roughly 5.2 mg/kg. In seawater, it is much more diluted, at about 0.9 ng/L.

Extracting dysprosium is a complex multi-step process. Most of the supply comes from monazite sand, which is a mixture of different phosphates. First, unwanted metals are removed through magnetic separation or a flotation process. Next, scientists use ion-exchange techniques to separate dysprosium from other rare-earth metals. To turn these separated ions into metal, they are reacted with fluorine or chlorine. This creates compounds like dysprosium fluoride (DyF3) or dysprosium chloride (DyCl3). These compounds are then placed in a tantalum crucible and heated in a helium atmosphere. They are reduced using calcium or lithium metals. Because of differences in density, the molten dysprosium separates from the other materials as it forms.

Dysprosium
Dysprosium

Naturally occurring dysprosium consists of seven different isotopes. These are versions of the element with different atomic masses. The isotopes are 156Dy, 158Dy, 160Dy, 161Dy, 162Dy, 163Dy, and 164Dy. All of these are considered stable. However, the last two are only theoretically stable, meaning the others might undergo alpha decay. The most abundant isotope is 164Dy, which makes up 28% of naturally occurring dysprosium. The rarest is 156Dy, at only 0.06%. Dysprosium is actually the heaviest element to have isotopes that are theoretically stable rather than just observationally stable.

History shows how difficult this element was to master. In 1886, the French chemist Paul Émile Lecoq de Boisbaudran first identified it in Paris. He was working with holmium oxide when he successfully separated dysprosium oxide. This was not easy; he had to attempt his procedure more than 30 times. He named the element after the Greek word *dysprositos*, which means "hard to get." It was not until the 1950s that Frank Spedding at Iowa State University developed ion-exchange techniques. These methods finally allowed scientists to isolate dysprosium in a pure form.

Dysprosium is essential for many modern technologies. It is used to make neodymium-iron-boron (NdFeB) magnets. By substituting up to 6% of the neodymium with dysprosium, the magnets become much more resistant to corrosion and high heat. This is vital for the motors in electric vehicles and the generators in wind turbines. It is also used in nuclear reactors. Because it has a high thermal neutron absorption cross-section, it is used in control rods. Furthermore, its high magnetic susceptibility makes it useful for data-storage devices like hard disks.

Beyond magnets and reactors, dysprosium has unique chemical properties. It reacts with water, forming dysprosium hydroxide. It also reacts vigorously with halogens at temperatures above 200 °C. When it dissolves in dilute sulfuric acid, it forms yellow Dy(III) ions.

Dysprosium-sulfate
Dysprosium-sulfate

Some of its compounds, like dysprosium oxide, are highly magnetic. This material is actually more magnetic than iron oxide. In advanced physics, dysprosium has been used to create a Bose-Einstein condensate and a 2-dimensional supersolid quantum gas. These discoveries help scientists understand the very strange rules of quantum mechanics.

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