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Dolomite (rock)

earth science Maturity 11-13 Next article →

Dolomite is a sedimentary carbonate rock. It contains a high percentage of the mineral dolomite, which has the chemical formula CaMg(CO3)2.

7092 pieskovna Dolinka pri Hradisti pod Vratnom dolomit
7092 pieskovna Dolinka pri Hradisti pod Vratnom dolomit

This rock is important because it can serve as a reservoir for oil and natural gas. This is possible because dolomite often has high porosity, meaning it has many tiny holes. While it is widespread, it is less common than limestone. You will rarely find it in Cenozoic rock beds, which are less than about 66 million years old.

Saaremaa dolomiit 1994 (04)
Saaremaa dolomiit 1994 (04)

Most dolomite forms through a process called dolomitization. This is the conversion of calcite into dolomite. This usually happens when magnesium replaces calcium in limestone or lime mud before it turns into solid rock. This process is chemically favorable, with a Gibbs free energy of about -2.2 kcal/mol. Because magnesium ions have a tightly bound hydration shell of water molecules, they are hard to use in crystal growth. For dolomitization to work, large volumes of magnesium-bearing fluids must flush through the pore spaces of the limestone. This allows for the simultaneous dissolution of calcite and the crystallization of dolomite.

Scientists have proposed several models to explain how this happens. The hypersaline model suggests that in closed basins, seawater evaporates. This leaves behind a dense brine with a high magnesium-to-calcium ratio. This brine sinks into limestone pores through seepage refluxion. Another idea is the mixing-zone model, where fresh meteoric water mixes with seawater. This increases the chemical activity of magnesium. Some research also suggests that sulfate-reducing bacteria living in oxygen-poor conditions can help precipitate dolomite.

Fossiliferous dolostone 1
Fossiliferous dolostone 1

There are different ways to describe the grains of dolomite. If the rock has well-formed grains with flat surfaces, it is called planar or idiotopic dolomite. If the grains are poorly formed with irregular surfaces, it is called nonplanar or xenotopic dolomite. Xenotopic dolomite likely forms through recrystallization at high temperatures. The texture of the rock can also tell us about its history. Many dolomites are secondary, meaning they formed by replacing limestone. In these cases, the original limestone texture might be perfectly preserved or completely destroyed.

Sthenarocalymene celebra - Arthropoda, Trilobita, Polymerida, Calymenidae - Silurian - Ohio, USA
Sthenarocalymene celebra - Arthropoda, Trilobita, Polymerida, Calymenidae - Silurian - Ohio, USA

Humans have been studying this rock for centuries. In the late 18th century, a French geologist named Déodat Gratet de Dolomieu distinguished it from limestone. He described its unique characteristics, and the mineral was later named after him. In March 1792, the Swiss chemist Nicolas Théodore de Saussure analyzed the mineral. He officially gave it the name dolomite. While some people use the term "dolostone" to describe the rock, this is controversial. The term dolomite has technical precedence because it was used for the rock in the 1700s.

Cirque de Mourèze, Hérault 32
Cirque de Mourèze, Hérault 32

Physically, dolomite has very specific traits. It is a soft rock with a Mohs hardness of 4 or less. It often looks granular, similar to grains of sugar. This sugary texture happens because dolomite takes up about 12% to 13% less volume than calcite. This reduction in volume increases the rock's porosity. Dolomite also has a distinct chemical reaction. If you drop dilute hydrochloric acid on it, it will bubble only feebly. This is much weaker than the vigorous bubbling seen in limestone.

Fossiliferous dolostone 1
Fossiliferous dolostone 1

Dolomite also affects the landscape through erosion. It is more resistant to erosion than many other rocks. This resistance helps create large features like the Niagara Escarpment.

Canadian Horseshoe Falls with city of Niagara Falls, Ontario in background
Canadian Horseshoe Falls with city of Niagara Falls, Ontario in background

Even though it is resistant, it can still develop solution features known as karst. These are landscapes shaped by the dissolving of rock. Because of its chemical makeup, dolomite often weathers to a dull yellow-brown color. This color is caused by the presence of ferrous iron within the rock.

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🖼️ Images & Media (6)
File:7092 pieskovna Dolinka pri Hradisti pod Vratnom dolomit.JPG
7092 pieskovna Dolinka pri Hradisti pod...
File:Canadian Horseshoe Falls with city of Niagara Falls, Ontario in background.jpg
Canadian Horseshoe Falls with city of...
File:Sthenarocalymene celebra - Arthropoda, Trilobita, Polymerida, Calymenidae - Silurian - Ohio, USA.jpg
Sthenarocalymene celebra - Arthropoda,...
File:Cirque de Mourèze, Hérault 32.jpg
Cirque de Mourèze, Hérault 32.jpg
File:Fossiliferous dolostone 1.jpg
Fossiliferous dolostone 1.jpg
File:Saaremaa dolomiit 1994 (04).jpg
Saaremaa dolomiit 1994 (04).jpg
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