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Dalton (unit)

physical science Maturity 11-13 Next article →

The dalton (symbol: Da) is a specialized unit used to measure mass at the atomic scale. It is also known as the unified atomic mass unit (symbol: u). This unit is essential because atoms and molecules are far too small for standard units like kilograms. Scientists use the dalton to describe the mass of discrete particles or the average mass of large groups. While it is a non-SI unit, it is officially accepted for use alongside the International System of Units. The term "unified" is important because it shows that both physicists and chemists agreed on its definition.

To understand how the dalton works, we must look at a specific standard. One dalton is defined as exactly 1/12th the mass of one unbound, neutral carbon-12 atom. For this definition to work, the atom must be in its nuclear and electronic ground state and at rest. This carbon-12 atom acts as a universal ruler for the microscopic world. Because the mass of this atom is a fixed reference, scientists can use it to calculate the mass of any other substance. For example, the mass of a single helium-4 atom is exactly 4.002602 Da. This precise relationship allows for incredibly accurate measurements in laboratory settings.

Scientists use different scales depending on the size of the object they are studying. For small atoms or molecules, the dalton is the standard choice. However, when dealing with massive biological structures, scientists use larger prefixes. They use the kilodalton (kDa) for medium molecules and the megadalton (MDa) for very large ones. A famous example is a protein called titin, which is one of the largest known proteins. It has a molecular mass between 3 and 3.7 megadaltons.

Using these different scales helps researchers manage the huge numbers involved in biology.

The history of this unit is a story of constant refinement. In 1803, John Dalton proposed using the mass of hydrogen as a natural unit. Later, in 1898, chemist Wilhelm Ostwald suggested using oxygen instead.

Johann Josef Loschmidt portrait plaque
Johann Josef Loschmidt portrait plaque

This oxygen-based scale was used for many years, including during Jean Perrin's experiments in 1909.

Jean Perrin 1926
Jean Perrin 1926

However, the discovery of oxygen isotopes in 1929 created a problem. Chemists and physicists began using different definitions of the oxygen mass, which caused confusion in high-precision science. This led to the search for a single, stable standard that both fields could trust.

In 1957, Alfred O. C. Nier suggested that carbon-12 would be a better standard. Carbon was already used in mass spectrometry, making it easier to work with. In 1961, the International Union of Pure and Applied Physics (IUPAP) and the International Union of Pure and Applied Chemistry (IUPAC) officially adopted the carbon-12 scale. This new unit was called the unified atomic mass unit to resolve the previous confusion. The shorter name "dalton" was later proposed in 1993. This name was eventually endorsed by the scientific community to make the unit easier to use with SI prefixes.

The dalton is also closely linked to the mole, a unit used to count large amounts of particles. In chemistry, the mass of one mole of a substance in grams is almost exactly equal to its average mass in daltons. For instance, one molecule of water has a mass of about 18.0153 Da. Consequently, one mole of water has a mass of about 18.0153 grams. While the 2019 redefinition of the SI units made this relationship an approximation rather than an exact identity, it remains very close for practical work. This connection allows scientists to bridge the gap between the mass of a single atom and the mass of a visible sample.

Understanding the dalton also requires looking at the internal structure of atoms. The mass of an atom is not just the sum of its protons and neutrons. It is also affected by the mass and binding energy of its electrons. For example, the mass of a hydrogen-1 atom is slightly different from the mass of a single proton plus a single electron. This difference, known as absolute mass excess, is usually very small, often less than 0.1%. However, in some cases like hydrogen-1, the difference is about 0.8%. These tiny variations are vital for scientists studying nuclear physics and the fundamental building blocks of the universe.

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