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Argon–argon dating

earth science Maturity 11-13 Next article →

Argon–argon dating is a highly precise method of radiometric dating. Scientists use this technique to determine the age of various geological materials. It was specifically invented to improve upon an older technique called potassium–argon (K/Ar) dating. The older K/Ar method was difficult because it required splitting a single sample into two parts. One part was measured for potassium, and the other was measured for argon. In contrast, the argon–argon method requires only one single rock fragment or mineral grain. This allows for a single measurement of argon isotopes to provide the necessary data.

The mechanism of this method relies on a process called neutron irradiation. First, scientists crush a rock sample to find tiny mineral crystals. They hand-select these crystals for a process inside a nuclear reactor. Inside the reactor, neutrons hit the sample to trigger an (n-p) reaction. This reaction converts stable potassium-39 (39K) into radioactive argon-39 (39Ar). This step is vital because it allows scientists to measure argon isotopes directly. By using this method, they can calculate the ratio between different types of argon.

Once the crystals are irradiated, they undergo a process called degassing. Scientists place the sample in a high-vacuum mass spectrometer. They use either a laser or a resistance furnace to heat the sample. This intense heat causes the crystal structure of the mineral to degrade. As the mineral melts, it releases trapped gases that were held inside. These gases can include water, nitrogen, or carbon dioxide from the atmosphere. Most importantly, the heat releases radiogenic argon, which is argon produced by radioactive decay.

To calculate a specific age, scientists must use a process called relative dating. The argon–argon method cannot determine an absolute age on its own. Instead, it must be compared to a standard of a known age. This standard is irradiated at the same time as the unknown sample. This allows scientists to determine the J-factor, which is a parameter of the irradiation. The J-factor represents the fluence, or the density, of the neutron bombardment. A denser flow of neutrons converts more potassium-39 into argon-39.

This dating method is most useful for metamorphic and igneous minerals. It is particularly effective for studying the thermal history of rocks. Different minerals have different closure temperatures, which are temperatures where they begin to trap gas. For example, biotite has a closure temperature of approximately 300°C. Muscovite has a higher closure temperature of about 400°C. Hornblende has an even higher closure temperature of around 550°C. Because of these differences, a single granite might show several different ages. These ages reflect when each mineral cooled below its specific temperature.

While powerful, the method requires careful interpretation and specific assumptions. Scientists assume that a rock has retained all of its radiogenic 40Ar after cooling. They also assume the sample was properly collected during the analysis. The abundance of radiogenic argon increases as a sample gets older. However, this increase follows an exponential decay based on the half-life of potassium-40. The half-life of potassium-40 is approximately 1.248 billion years. This long duration makes the method useful for studying very old geological events.

Recent scientific work has even led to the recalibration of historical dates. Researchers like Kuiper et al. discovered that a small correction was necessary. They found that a correction of 0.65% was needed for certain calculations. This adjustment changed our understanding of the Cretaceous–Paleogene extinction event. Previously, scientists thought the dinosaurs died out 65.0 or 65.5 million years ago. Thanks to these refinements, the event is now dated to 66.0–66.1 Ma. This shows how constant refinement makes our geological history more accurate.

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