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Liquid hydrogen

physical science Maturity 9-11

Some gas can turn into a liquid.

Linde-Wasserstofftank.JPG
Linde-Wasserstofftank.JPG
This happens when it gets very cold. It is used to help big rockets fly. This fuel helps us reach space. It is a very cool thing to see. Do you like looking at the stars?

44 words

Hydrogen is a gas. It can turn into a liquid.

Linde-Wasserstofftank.JPG
Linde-Wasserstofftank.JPG
This happens when it gets very cold. Storing it as a liquid saves space.
Hydrogen Tank - GPN-2000-001458.jpg
Hydrogen Tank - GPN-2000-001458.jpg
It is used as fuel for big rockets. NASA uses it to help fly. The liquid fuel can even make water when it burns.
DOT Hazardous Material Placard liquid hydrogen.jpg
DOT Hazardous Material Placard liquid hydrogen.jpg
It must stay in special, warm-keeping tanks. This keeps the liquid from turning back into gas. It is a powerful tool for space travel.

83 words

Hydrogen is a gas found in nature. It can turn into a liquid.

Linde-Wasserstofftank.JPG
Linde-Wasserstofftank.JPG
To do this, it must get very cold. It must reach a temperature below 33 K.
Hydrogen Tank - GPN-2000-001458.jpg
Hydrogen Tank - GPN-2000-001458.jpg
Storing it as a liquid saves a lot of space. This makes it great for rocket fuel. NASA and the U.S. Air Force use large tanks for this. Some tanks hold up to 3.8 million liters.
DOT Hazardous Material Placard liquid hydrogen.jpg
DOT Hazardous Material Placard liquid hydrogen.jpg

There are two types of hydrogen molecules. We call these spin isomers. One type is called orthohydrogen. The other is parahydrogen. Parahydrogen is more stable. When orthohydrogen turns into parahydrogen, it lets out heat. This heat can make the liquid boil away. To stop this, workers use a catalyst. A catalyst is something that helps a change happen faster. They use it to make the hydrogen parahydrogen during the cooling step. This helps keep the liquid safe in insulated tanks. Liquid hydrogen is very powerful. It has more energy than gasoline or diesel. It can even be used to power ships and submarines.

179 words

Liquid hydrogen is the liquid state of the element hydrogen. Hydrogen is usually found as a gas in nature.

Linde-Wasserstofftank.JPG
Linde-Wasserstofftank.JPG
Turning it into a liquid is a big job. It requires cooling the gas below a critical point of 33 K. To be a fully liquid at normal air pressure, it must reach -253 degrees Celsius.
Hydrogen Tank - GPN-2000-001458.jpg
Hydrogen Tank - GPN-2000-001458.jpg
Storing hydrogen as a liquid takes up much less space than storing it as a gas. This makes it a very useful way to hold large amounts of energy. However, the liquid is not very dense compared to other common fuels.

There is a special way liquid hydrogen works with heat. Hydrogen has two forms called spin isomers. These are called orthohydrogen and parahydrogen. At room temperature, most hydrogen is orthohydrogen. When it is cooled to become a liquid, it wants to change into parahydrogen. This change releases heat, which is called an exothermic reaction. This heat can cause the liquid to boil away.

Liquid hydrogen bubblechamber.jpg
Liquid hydrogen bubblechamber.jpg
To prevent this, workers use a catalyst during the cooling process. A catalyst helps the hydrogen turn into the stable parahydrogen form early. This keeps the liquid from boiling off too quickly in storage.

Scientists have studied hydrogen for a long time. In 1885, Zygmunt Florenty Wróblewski found the critical temperature and pressure of hydrogen. Later, in 1898, James Dewar successfully liquefied hydrogen. He used his invention called a vacuum flask to do this.

DOT Hazardous Material Placard liquid hydrogen.jpg
DOT Hazardous Material Placard liquid hydrogen.jpg
In 1929, Paul Harteck and Karl Friedrich Bonhoeffer found a way to make the stable parahydrogen form. These discoveries helped us understand how to use this fuel today.

Liquid hydrogen is used in many amazing ways. It is a common fuel for rockets used by NASA and the U.S. Air Force. Some of these large tanks can hold up to 3.8 million liters. In a rocket engine, the liquid hydrogen cools the nozzle before it burns. It mixes with an oxidizer, like liquid oxygen, to create a powerful blast. The exhaust from this burn is mostly water vapor. This makes it a very clean fuel for many uses. It can also power ships, submarines, and even some concept cars.

You can think of liquid hydrogen as a super-powered version of the fuel in a car. It has much more energy than gasoline or diesel. Because it is so cold, it must be kept in special insulated containers. These containers act like a very strong thermos to keep the heat out. If the liquid gets too warm, it can turn back into a gas. It is also important to handle it carefully because it is very flammable. Even though it is powerful, it is a substance that requires great care and special tools.

457 words

Liquid hydrogen is the liquid state of the element hydrogen. In nature, hydrogen is usually found in the molecular form of H2. It is a highly concentrated way to store hydrogen energy. Storing the element as a liquid takes up much less space than storing it as a gas. However, liquid hydrogen has a very low density. Its density is only 70.85 kg/m3 at 20 K. This makes its volumetric energy density much lower than other fuels.

Linde-Wasserstofftank.JPG
Linde-Wasserstofftank.JPG

To turn hydrogen into a liquid, it must be cooled significantly. It must reach a critical point of 33 K to exist as a liquid. To be fully liquid at atmospheric pressure, it must be cooled to -253 degrees Celsius. One common method for obtaining liquid hydrogen uses a compressor. This machine looks and works much like a jet engine. Once liquefied, the substance can be kept in thermally insulated containers. Even with this insulation, it can leak away at a rate of about 1% per day.

Hydrogen Tank - GPN-2000-001458.jpg
Hydrogen Tank - GPN-2000-001458.jpg

Hydrogen exists in two different spin isomers. These are called orthohydrogen and parahydrogen. In these molecules, the two nuclei can have different spin states. In orthohydrogen, the nuclear spins are parallel. In parahydrogen, the nuclear spins are antiparallel. At room temperature, 75% of hydrogen is orthohydrogen. However, parahydrogen is the more stable state. The lowest energy state for liquid hydrogen consists of 99.79% parahydrogen.

Liquid hydrogen bubblechamber.jpg
Liquid hydrogen bubblechamber.jpg

When hydrogen is cooled, orthohydrogen converts to parahydrogen. This is an exothermic reaction, which means it releases heat. This released heat can cause the liquid to boil off. To prevent this, workers use a catalyst during the liquefaction process. A catalyst is a substance that speeds up a chemical change. Common catalysts include iron(III) oxide, activated carbon, or nickel compounds. This converts the hydrogen to the parahydrogen form early. This prevents excessive boil-off during long-term storage.

Scientists have made many important discoveries regarding hydrogen. In 1885, Zygmunt Florenty Wróblewski published the critical temperature and pressure of hydrogen. In 1898, James Dewar successfully liquefied hydrogen. He used regenerative cooling and his invention, the vacuum flask. Later, in 1929, Paul Harteck and Karl Friedrich Bonhoeffer achieved the first synthesis of stable parahydrogen. These steps allowed us to understand and use liquid hydrogen in modern technology.

DOT Hazardous Material Placard liquid hydrogen.jpg
DOT Hazardous Material Placard liquid hydrogen.jpg

Liquid hydrogen is a vital fuel for rocketry. NASA and the U.S. Air Force use large liquid hydrogen tanks. Some of these individual tanks hold up to 3.8 million liters. In most rocket engines, the liquid hydrogen first cools the nozzle. Then, it is mixed with an oxidizer, which is usually liquid oxygen. They burn together to produce water, traces of ozone, and hydrogen peroxide. Many engines run fuel-rich to reduce nozzle erosion. This also increases the specific impulse of the engine.

Liquid hydrogen bubblechamber.jpg
Liquid hydrogen bubblechamber.jpg

Beyond rockets, liquid hydrogen has many other uses. It can power internal combustion engines or fuel cells. The MF Hydra ferry uses liquid hydrogen for power. Some submarines, like the Type 212, also use it. It is even being studied as a zero-carbon fuel for aircraft. Scientists also use it to cool neutrons for neutron scattering. This works because hydrogen nuclei and neutrons have similar masses. This allows for maximum kinetic energy exchange during collisions.

Liquid hydrogen bubblechamber.jpg
Liquid hydrogen bubblechamber.jpg

Safety is a major concern when handling liquid hydrogen. It is extremely cold, which can cause cold burns. It is also very flammable and can detonate when mixed with air. Recently vaporized hydrogen is very cold and heavier than air. This can create flammable mixtures near the ground. There is also a risk involving atmospheric oxygen. The liquid is so cold it can solidify oxygen on the outside of containers. This creates an oxygen-rich environment that can spontaneously ignite materials.

DOT Hazardous Material Placard liquid hydrogen.jpg
DOT Hazardous Material Placard liquid hydrogen.jpg

628 words
🖼️ Images & Media (4)
File:Liquid_hydrogen_bubblechamber.jpg
Liquid_hydrogen_bubblechamber.jpg
File:Hydrogen Tank - GPN-2000-001458.jpg
Hydrogen Tank - GPN-2000-001458.jpg
File:Linde-Wasserstofftank.JPG
Linde-Wasserstofftank.JPG
File:DOT Hazardous Material Placard liquid hydrogen.jpg
DOT Hazardous Material Placard liquid hydrogen.jpg
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